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pochemuha
3 years ago
7

vaporized at 100°C and 1 atmosphere pressure. Assuming ideal gas 1 g mole of water is behavior calculate the work done and compa

re this with the latent heat (40.57 kJ/mole). Why is the heat so much larger than the work?
Chemistry
1 answer:
Vesna [10]3 years ago
7 0

Answer:

q = 40.57 kJ; w = -3.10 kJ; strong H-bonds must be broken.

Explanation:

1. Heat absorbed

q = nΔH = 1 mol × (40.57 kJ/1 mol) = 40.57 kJ

2. Change in volume

V(water) = 0.018 L

pV = nRT

1 atm × V = 1 mol × 0.082 06 L·atm·K⁻¹mol⁻¹ × 373.15 K

V = 30.62 L

ΔV = V(steam) - V(water) = 30.62 L - 0.018 L = 30.60 L

3. Work done

w = -pΔV = - 1 atm × 30.60 L = -30.60 L·atm

w = -30.60 L·atm × (101.325 J/1 L·atm) = -3100 J = -3.10 kJ

4. Why the difference?

Every gas does 3.10 kJ of work when it expands at 100 °C and 1 atm.

The difference is in the heat of vaporization. Water molecules are strongly hydrogen bonded to each other, so it takes a large amount of energy to convert water from the liquid phase to the vapour phase.

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How many grams of water can be formed from the reaction of 8.76 grams of H2 with 10.5 liters of O2 (at STP) according to the bal
Kisachek [45]

Answer:

16.9g of H₂O can be formed

Explanation:

Based on the chemical reaction, 2 moles of H₂ react per mole of O₂. To anser this question we must find limiting reactant converting the mass and volume of each reactant to moles:

<em>Moles H₂ -Molar mass: 2.016g/mol-:</em>

8.76g * (1mol / 2.016g) = 4.345 moles

<em>Moles O₂:</em>

PV = nRT

PV/RT = n

P = 1atm at STP

V = 10.5L

R = 0.082atmL/molK

T = 273.15K at STP

n = 1atm*10.5L / 0.082atmL/molK*273.15K

n = 0.469 moles of oxygen

For a complete reaction of 4.345 moles moles of hydrogen are required:

4.345 moles H2 * (1mol O2 / 2mol H2) = 2.173 moles of O2 are required. As there are just 0.469 moles, Oxygen is limiting reactant

Now, 1 mole of O2 produce 2 moles of H2O. 0.469 moles will produce:

0.469 moles O₂ * (2 moles H₂O / 1mol O₂) = 0.938 moles H₂O.

The mass is -Molar mas H₂O = 18.01g/mol-:

0.938 moles * (18.01g/mol) =

<h3>16.9g of H₂O can be formed</h3>
8 0
3 years ago
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olga nikolaevna [1]

Answer:

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Explanation:

For a nonelementary reaction, the reaction equation is described as the sum of all the steps involved. All these steps constitute the reaction mechanism. Each step in the mechanism is an elementary reaction. The rate law of the overall reaction involves the rate determining step (slowest step) in the reaction sequence.

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The two steps in the mechanism are

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N2O2(g) +O2(g) -------> 2NO2(g) (slow)

Summing all the steps and cancelling out the intermediate N2O2(g), we obtain the reaction equation;

2NO(g) + O2(g) ---------> 2NO2(g)

Hence the answer.

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