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jasenka [17]
3 years ago
11

During an experiment, 104 grams of calcium carbonate reacted with an excess amount of hydrochloric acid. If the percent yield of

the reaction was 80.15%, what was the actual amount of calcium chloride formed? CaCO3 + HCl → CaCl2 + CO2 + H2O 90.1 grams 92.4 grams 109.2 grams 115.3 grams
Chemistry
1 answer:
postnew [5]3 years ago
7 0

Answer:

92.4 grams.

Explanation:

  • From the balanced reaction:

<em>CaCO₃ + 2HCl → CaCl₂ + CO₂ + H₂O,</em>

1.0 mole of CaCO₃ reacts with 2.0 moles of HCl to produce 1.0 mole of CaCl₂, 1.0 mole of CO₂, and 1.0 mole of H₂O.

  • We need to calculate the no. of moles of (104 g) of CaCO₃:

<em>no. of moles of CaCO₃ = mass/molar mass</em> = (104 g)/(100.08 g/mol) = <em>1.039 mol.</em>

<u><em>Using cross multiplication:</em></u>

1.0 mole of CaCO₃ produce → 1.0 mole of CaCl₂.

∴ 1.039 mole of CaCO₃ produce → 1.039 mole of CaCl₂.

∴ The amount of CaCl₂ produced = no. of moles x molar mass = (1.039 mol)(110.98 g/mol) = 114.3 g.

∵ percent yield of the reaction = [(actual yield)/(theoretical yield)] x 100.

Percent yield of the reaction = 80.15%, theoretical yield = 115.3 g.

<em>∴ actual yield = [(percent yield of the reaction)(theoretical yield)]/100 </em>= [(80.15%)/(115.3 g)] / 100 = <em>92.42 g ≅ 92.4 g.</em>

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<u>Answer:</u>

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<u>For B:</u> The standard Gibbs free energy of the reaction is -8.50\times 10^5J

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<u>Explanation:</u>

  • <u>For A:</u>

The given chemical reaction follows:

2Li(s)+Cl_2(g)\rightarrow 2Li^+(aq.)+2Cl^-(aq.)

The given half reaction follows:

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<u>Reduction half reaction:</u>  Cl_2(g)+2e^-\rightarrow 2Cl^-(aq.);E^o_{Cl_2/2Cl^-}=+1.36V

The substance having highest positive E^o potential will always get reduced and will undergo reduction reaction.

Here, chlorine will undergo reduction reaction will get reduced.

Substance getting oxidized always act as anode and the one getting reduced always act as cathode.

To calculate the E^o_{cell} of the reaction, we use the equation:

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Hence, the standard cell potential of the reaction is 4.4 V

  • <u>For B:</u>

Relationship between standard Gibbs free energy and standard electrode potential follows:

\Delta G^o=-nFE^o_{cell}

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n = number of electrons transferred = 2mol\text{ e}^-

F = Faradays constant = 96500J/V.mol\text{ e}^-

E^o_{cell} = standard cell potential = 4.4 V

Putting values in above equation, we get:

\Delta G^o=-2\times 96500\times 4.4=-849200J=-8.50\times 10^5J

Hence, the standard Gibbs free energy of the reaction is -8.50\times 10^5J

  • <u>For C:</u>

For a reaction to be spontaneous, the standard Gibbs free energy change of the reaction must be negative.

From above, the standard Gibbs free energy change of the reaction is coming out to be negative.

Hence, the reaction is spontaneous as written.

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