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DerKrebs [107]
3 years ago
10

Which bond from each set has the greatest bond energy and why?. A.) N-O or N-F. B.) B-F or B-Cl. C.) B-C or O-F. D.) C-O or C=O.

E.) P-Br or P-Cl
Chemistry
2 answers:
Vikki [24]3 years ago
7 0

Answer:

    A) N-F,  B) B-F,  C) O-F, D) C=O, E) P-Cl.

Explanation:

Bond energy is the energy that is to break the molecule apart. Bond energy affected by the electronegativity and no. of bonds.

A) N-F bond is more powerful than N-O because Fluorine is the highest electronegative element in the periodic table.

B) B-F has strongest bond than B-Cl, due to higher electronegativity of fluorine.

C) O-F has highest bond energy than B-C, because O is strong covalently bonded with fluorine which is the highest electronegative.

D) C=O has highest bond energy, because double bond has required more energy to break than the single bond.

E) P-Cl has high bond energy than the P-Br, because Cl has small size and more electronegative than Br.

Solnce55 [7]3 years ago
5 0
A) N-F becasue F ismore electronegative so the covalent bond is stronger
B) B-Cl because Cl is a smaller atom than Br so the covalent bond is stronger 
C) O-F because the atoms are more electronegative so the bond is stronger.
D) C=O because the double bond is stronger than the single bond.
E) P-Cl because Cl is smaller than Br so the electrostatic force of attraction between the positive nucleus and the bonding electrons is stronger, thus the covalent bond is stronger 

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Explanation:

We'll begin by writing the balanced equation for the reaction. This is illustrated below:

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Suppose a solution is prepared by dissolving 15.0 g NaOH in 0.150 L of 0.250 M nitric acid. What is the final concentration of O
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Answer:

2.25 M is the final concentration of hydroxide ions ions in the solution after the reaction has gone to completion.

Explanation:

Moles of NaOH = \frac{15.0 g}{40 g/mol}=0.375 mol

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Volume of the nitric solution = 0.150 L

Moles of nitric acid = n

Molarity=\frac{Moles}{Volume(L)}

n=0.250 M\times 0.150 L=0.0375 mol

NaOH+HNO_3\rightarrow NaNO_3+H_2O

According to reaction, 1 mole of nitric acid recats with 1 mole of NaOH, then 0.0375 moles of nitric acid will react with :

\frac{1}{1}\times 0.0375 mol of NaOH

Moles of NaOH left unreacted  in the solution =

= 0.375 mol - 0.0375 mol = 0.3375 mol

NaOH(aq)\rightarrow Na^+(aq)+OH^-(aq)

1 mole of sodium hydroxide gives 1 mol of sodium ions and 1 mole of hydroxide ions.

Then 0.3375 moles of NaOH will give :

1\times 0.3375 moles=0.3375 mol of hydroxide ion

The molarity of hydroxide ion in solution ;

=\frac{0.3375 mol}{0.150 L}=2.25 M

2.25 M is the final concentration of hydroxide ions ions in the solution after the reaction has gone to completion.

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3 years ago
Consider the following reaction: A(g)⇌2B(g). Find the equilibrium partial pressures of A and B for each of the following differe
Illusion [34]

Answer:

a. Kp=1.4

P_{A}=0.2215 atm

P_{B}=0.556 atm

b.Kp=2.0 * 10^-4

P_{A}=0.495atm

P_{B}=0.00995 atm

c.Kp=2.0 * 10^5

P_{A}=5*10^{-6}atm

P_{B}=0.9999 atm

Explanation:

For the reaction  

A(g)⇌2B(g)

Kp is defined as:

Kp=\frac{(P_{B})^{2}}{P_{A}}

The conditions in the system are:

          A                    B

initial   0                1 atm

equilibrium x       1atm-2x

At the beginning, we don’t have any A in the system, so B starts to react to produce A until the system reaches the equilibrium producing x amount of A. From the stoichiometric relationship in the reaction we get that to produce x amount of A we need to 2x amount of B so in the equilibrium we will have 1 atm – 2x of B, as it is showed in the table.    

Replacing these values in the expression for Kp we get:

Kp=\frac{(1-2x)^{2}}{x}

Working with this equation:

x*Kp=(1-2x)^{2} - -> x*Kp=4x^{2}-4x+1- - >4x^{2}-(4+Kp)*x+1=0

This last expression is quadratic expression with a=4, b=-(4+Kp) and c=1

The general expression to solve these kinds of equations is:

x=\frac{-b(+-)*\sqrt{(b^{2}-4ac)}}{2a} (equation 1)

We just take the positive values from the solution since negative partial pressures don´t make physical sense.

Kp = 1.4

x_{1}=\frac{(1.4+4)+\sqrt{(-(1.4+4)^{2}-4*4*1)}}{2*4}=1.128

x_{1}=\frac{(1.4+4)-\sqrt{(-(1.4+4)^{2}-4*4*1)}}{2*4}=0.2215

With x1 we get a partial pressure of:

P_{A}=1.128 atm

P_{B}=1-2*1.128 = -1.256 atm

Since negative partial pressure don´t make physical sense x1 is not the solution for the system.

With x2 we get:

P_{A}=0.2215 atm

P_{B}=1-2*0.2215 = 0.556 atm

These partial pressures make sense so x2 is the solution for the equation.

We follow the same analysis for the other values of Kp.

Kp=2*10^-4

X1=0.505

X2=0.495

With x1

P_{A}=0.505atm

P_{B}=1-2*0.505 = -0.01005 atm

Not sense.

With x2

P_{A}=0.495atm

P_{B}=1-2*0.495 = 0.00995 atm

X2 is the solution for this equation.  

Kp=2*10^5

X1=50001

X2=5*10^{-6}

With x1

P_{A}=50001atm

P_{B}=1-2*50001=-100001atm

Not sense.

With x2

P_{A}= 5*10^{-6}atm

P_{B}=1-2*5*10^{-6}= 0.9999 atm

X2 is the solution for this equation.  

8 0
3 years ago
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