Answer:
- Alanine = 5.61 mmoles
- Leucine = 3.81 mmoles
- Tryptophan = 2.45 mmoles
- Cysteine = 4.13 mmoles
- Glutamic acid = 3.40 mmoles
Explanation:
Mass / Molar mass = Moles
Milimoles = Mol . 1000
500 mg / 1000 = 0.5 g
- Alanine = 0.5 g / 89 g/m → 5.61x10⁻³ moles . 1000 = 5.61mmoles
- Leucine = 0.5 g / 131 g/m → 3.81 x10⁻³ moles . 1000 = 3.81 mmoles
- Tryptophan = 0.5 g / 204 g/m → 2.45x10⁻³ moles . 1000 = 2.45 mmoles
- Cysteine = 0.5 g / 121 g/m → 4.13x10⁻³ moles . 1000 = 4.13 mmoles
- Glutamic acid = 0.5 g 147 g/m → 3.40x10⁻³ moles . 1000 = 3.4 mmoles
Answer:
a. A reaction in which the entropy of the system increases can be spontaneous only if it is endothermic.
Explanation:
The change in free energy (ΔG) that is, the <u>energy available to do work</u>, of a system for a constant-temperature process is:

-
When ΔG < 0 the reaction is spontaneous in the forward direction.
- When ΔG > 0 the reaction is nonspontaneous. The reaction is
spontaneous in the opposite direction.
- When ΔG = 0 the system is at equilibrium.
If <u>both ΔH and ΔS are positive</u>, then ΔG will be negative only when the TΔS term is greater in magnitude than ΔH. This condition is met when T is large.
Explanation:
The reaction equation will be as follows.

Hence, the expression for
is as follows.
![K_{a} = \frac{[H_{2}SO^{-}_{4}][H^{+}]}{[H_{3}AsO_{4}]}](https://tex.z-dn.net/?f=K_%7Ba%7D%20%3D%20%5Cfrac%7B%5BH_%7B2%7DSO%5E%7B-%7D_%7B4%7D%5D%5BH%5E%7B%2B%7D%5D%7D%7B%5BH_%7B3%7DAsO_%7B4%7D%5D%7D)
Let us assume that the concentration of both
and
is x.

x = 0.01118034
This means that the concentration of
is 0.01118034.
Since, we know that the relation between pH and concentration of hydrogen ions is as follows.
pH = ![-log [H^{+}]](https://tex.z-dn.net/?f=-log%20%5BH%5E%7B%2B%7D%5D)
= 
= 1.958
Thus, we can conclude that the pH of a 0.500 M solution of arsenic acid is 1.958.