Osmosis deals only with D. Water. Diffusion and Osmosis are relatively the same thing besides the fact that water is largely incorporated with the osmosis.
A is a model of a decomposition reaction
It has the same composition throughout, unlike a heterogeneous which has visibly separate substances

1 mole of nitric acid produce 1 mole of ammonium nitrate.
moles in 5000 kg of ammonium nitrate :
( molecular mass of ammonium nitrate is 80 gm/mol )
So, number of moles of nitric acid required are also 62500 moles.
Mass of 62500 moles of nitric acid :

Hence, this is the required solution.
1.2*104 is 12000 it is easy just try ur best