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svetoff [14.1K]
3 years ago
15

We are all familiar with the general principles of operation of an internal combustion engine: the combustion of fuel drives out

the piston. It is possible to imagine engines that use reactions other than combustions, and we need to assess the work they can do. A chemical reaction takes place in a container of cross-sectional area 100.0 cm^2; the container has a piston at one end. As a result of the reaction, the piston is pushed out through 10 cm against a constant external pressure of 100 kPa. Calculate the work done by the system in Joules.
Chemistry
1 answer:
Alexus [3.1K]3 years ago
7 0

Answer:

The work done by the system is 100 J

Explanation:

Given details

The cross sectional area of the of the container is A = 100.0 cm^2 = 0.01m²

The total distance pushed by the piston is d = 10 cm = 0.10m

The total external pressure by which piston pushed is P = 100 kPa

From above data, the following relation can be used to determine the change in volume of the container

∆V = A * d

∆V = 0.01 * 0.10 = 0.001 m³

By using the following relation, the work done by the system is calculated as;

Work done W = P * ∆V

W = 100 * 0.001 = 0.1 kJ = 100 J

The work done by the system is 100 J

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Answer:

1,070.41 grams of DDT will be formed .Explanation:

1) 2 C_6H_5Cl + C_2HOCl_3\rightarrow C_{14}H_9Cl_5 + H_2O

Moles of chlorobenzene = \frac{1197 g}{112.5 g/mol}=10.64 mol

According to reaction, 2 moles of chloro benzene reacts with 1 mole of chloral . Then 10.64 moles of chloro benzene will react with :

\frac{1}{2}\times 10.64 mol=5.32 mole of chloral

2) Moles of chloral = \frac{456 g}{147.5 g/mol}=3.0915 mol

According to reaction, 1 moles of chloral reacts with 2 mole of chlorobenzene . Then 3.0915 moles of chloral will react with :

\frac{2}{1}\times 3.0915 mol=6.1830 mol of chloro benzene

As we can see that chloral is in limiting amount and chloro benzene is in excessive amount. So, amount of DDT will depend upon amount of chloral.

According to reaction, 1 mole chloral gives 1 mole DDT.Then 3.0195 moles of chloral will give :

\frac{1}{1}\times 3.0195 mol=3.0195 mol

Mass of 3.0195 moles of DTT :

3.0195 mol × 354.5 g/mol = 1,070.41 g

1,070.41 grams of DDT will be formed .

3 0
3 years ago
The temperature of a sample of water changes from 10°C to 20°C when the water absorbs 100 calories of heat. What is the mass of
Vlad1618 [11]

Answer:

10 g

Explanation:

Right from the start, just by inspecting the values given, you can say that the answer will be  

10 g

.

Now, here's what that is the case.

As you know, a substance's specific heat tells you how much heat is needed to increase the temperature of  

1 g

of that substance by  

1

∘

C

.

Water has a specific heat of approximately  

4.18

J

g

∘

C

. This tells you that in order to increase the temperature of  

1 g

of water by  

1

∘

C

, you need to provide  

4.18 J

of heat.

Now, how much heat would be required to increase the temperature of  

1 g

of water by  

10

∘

C

?

Well, you'd need  

4.18 J

to increase it by  

1

∘

C

, another  

4.18 J

to increase it by another  

1

∘

C

, and so on. This means that you'd need

4.18 J

×

10

=

41.8 J

to increase the temperature of  

1 g

of water by  

10

∘

C

.

Now look at the value given to you. If you need  

41.8 J

to increase the temperature of  

1 g

of water by  

10

∘

C

, what mass of water would require  

10

times as much heat to increase its temperature by  

10

∘

C

?

1 g

×

10

=

10 g

And that's your answer.

Mathematically, you can calculate this by using the equation

q

=

m

⋅

c

⋅

Δ

T

 

, where

q

- heat absorbed/lost

m

- the mass of the sample

c

- the specific heat of the substance

Δ

T

- the change in temperature, defined as final temperature minus initial temperature

Plug in your values to get

418

J

=

m

⋅

4.18

J

g

∘

C

⋅

(

20

−

10

)

∘

C

m

=

418

4.18

⋅

10

=

10 g

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