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svetoff [14.1K]
3 years ago
15

We are all familiar with the general principles of operation of an internal combustion engine: the combustion of fuel drives out

the piston. It is possible to imagine engines that use reactions other than combustions, and we need to assess the work they can do. A chemical reaction takes place in a container of cross-sectional area 100.0 cm^2; the container has a piston at one end. As a result of the reaction, the piston is pushed out through 10 cm against a constant external pressure of 100 kPa. Calculate the work done by the system in Joules.
Chemistry
1 answer:
Alexus [3.1K]3 years ago
7 0

Answer:

The work done by the system is 100 J

Explanation:

Given details

The cross sectional area of the of the container is A = 100.0 cm^2 = 0.01m²

The total distance pushed by the piston is d = 10 cm = 0.10m

The total external pressure by which piston pushed is P = 100 kPa

From above data, the following relation can be used to determine the change in volume of the container

∆V = A * d

∆V = 0.01 * 0.10 = 0.001 m³

By using the following relation, the work done by the system is calculated as;

Work done W = P * ∆V

W = 100 * 0.001 = 0.1 kJ = 100 J

The work done by the system is 100 J

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<h3>1</h3>

Species shown in bold are precipitates.

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  • Ca(NO₃)₂ + Na₂C₂O₄ → CaC₂O₄ + 2 NaNO₃
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<h3>2</h3>

A double replacement reaction takes place only if it reduces in the concentration of ions in the solution. For example, the reaction between Ca(NO₃)₂ and KOH produces Ca(OH)₂. Ca(OH)₂ barely dissolves. The reaction has removed Ca²⁺ and OH⁻ ions from the solution.

Some of the reactions lead to neither precipitates nor gases. They will not take place since they are not energetically favored.


<h3>3</h3>

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Both Ca(NO₃)₂ and Zn(NO₃)₂ react with KOH. However, between the two precipitates formed, Ca(OH)₂ is more soluble than Zn(OH)₂.

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<h3>4</h3>

Compare the second and third row:

Cu(NO₃)₂ reacts with KI, but Ni(NO₃)₂ does not. Thus, add equal amount of KI to the two unknowns. The solution that forms precipitate shall belong to Cu(NO₃)₂.

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