Answer:
6.48 L
Explanation:
From the question,
Applying
PV/T = P'V'/T'......................... Equation 1
P = initial pressure of the helium balloon, V = Initial volume of the balloon, T = Initial temperature of the balloon, P' = Final pressure of the balloon, T' = Final temperature of the balloon, V' = Final volume of the balloon.
make V' the subject of the equation
V' = PVT'/P'T......................... Equation 2
Given: P = 1 atm, V = 4.5 L, T' = 253 K, T= 293 K, P' = 0.6 atm
Substitute these values into equation 2
V' = (4.5×1×253)/(0.6×293)
V' = 1138.5/175.8
V' = 6.48 L
Mass of copper : 0.165 g
<h3>Further explanation</h3>
Given
5.0 A over 100 seconds
Required
Mass of copper
Solution
Faraday's law:
<em>The mass of the substance formed at each electrode is proportional to the electric current flowing in the electrolysis</em>
<em />
<em />
e = Ar / valence = eqivalent weight
i = current
t = time
W = weight
CuSO₄ ----> Cu²⁺ + SO₄²⁻
Cu ----> Cu²⁺ + 2e
e = Ar/2
= 63,5/2 = 31,75
Answer:
CH₂ ; 67.1 %
Explanation:
To determine the empirical formula we need to find what the mole ratio is in whole numbers of the atoms in the compound. To do that we will first need the atomic weights of C and H and then perform our calculation
Assume 100 grams of the compound.
# mol C = 85.7 g / 12.01 g/mol = 7.14 mol
# mol H = 14.3 g / 1.008 g/mol = 14.19 mol
The proportion is 14.9 mol H/ 7.14 mol C = 2 mol H/ 1 mol C
So the empirical formula is CH₂
For the second part we will need to first calculate the theoretical yield for the 12.03 g NaBH₄ reacted and then calculate the percent yield given the 0.295 g B₂H₆ produced.
We need to calculate the moles of NaBH₄ ( M.W = 37.83 g/mol )
1.203 g NaBH₄ / 37.83 g/mol = 0.0318 mol
Theoretical yield from balanced chemical equation:
0.0318 mol NaBH₄ x 1 mol B₂H₆ / mol NaBH₄ = 0.0159 mol B₂H₆
Theoretical mass yield B₂H₆ = 0.0159 mol x 27.66 g/ mol = 0.440 g
% yield = 0.295 g/ 0.440 g x 100 = 67.1 %
Answer:
1. The product has a higher Rf value on a silica gel TLC plate because it is more polar than the starting methyl benzoate.
2. False
3. True
Explanation:
In chromatography, there is a stationary phase and a mobile phase. The ratio of the distance moved by a component and the distance moved by the solvent gives the retention factor (Rf).
Since silica gel is a polar solvent, it will retain the more polar product methyl m-nitrobenzoate compared to the methyl benzoate starting material.
In comparing the electrophillic aromatic substitution of m-nitrobenzoate and methyl benzoate, we must remember that the presence of electron withdrawing groups (such as -NO2 and -CHO) on the aromatic compound deactivates the compound towards electrophillic aromatic substitution hence, methyl m-nitrobenzoate is less reactive than methyl benzoate in Electrophilic Aromatic Substition and Methyl benzoate is less reactive than benzene in Electrophilic Aromatic Substition
