Answer:
1.14atm
Explanation:
Given parameters:
V1 = 250cm³ ;
1000cm³ = 1dm³; so this is 0.25dm³
P1 = 760torr
760torr = 1atm
V2 = 220cm³ ; 0.22dm³
Unknown:
New pressure = ?
Solution:
To solve this problem, we apply Boyle's law and we use the expression below:
P1 V1 = P2V2
The unknown is P2;
1 x 0.25 = P2 x 0.22
P2 = 1.14atm
When it comes to equilibrium reactions, it useful to do ICE analysis. ICE stands for Initial-Change-Equilibrium. You subtract the initial and change to determine the equilibrium amounts which is the basis for Kc. Kc is the equilibrium constant of concentration which is just the ratio of products to reactant.
Let's do the ICE analysis
2 NH₃ ⇄ N₂ + 3 H₂
I 0 1.3 1.65
C +2x -x -3x
-------------------------------------
E 0.1 ? ?
The variable x is the amount of moles of the substances that reacted. You apply the stoichiometric coefficients by multiplying it by x. Now, we can solve x by:
Equilibrium NH₃ = 0.1 = 0 + 2x
x = 0.05 mol
Therefore,
Equilibrium H₂ = 1.65 - 3(0.05) = 1.5 molEquilibrium N₂ = 1..3 - 0.05 = 1.25 mol
For the second part, I am confused with the given reaction because the stoichiometric coefficients do not balance which violates the law of conservation of mass. But you should remember that the Kc values might differ because of the stoichiometric coefficient. For a reaction: aA + bB ⇄ cC, the Kc for this is
![K_{C} = \frac{[ C^{c} ]}{[ A^{a} ][ B^{b} ]}](https://tex.z-dn.net/?f=%20K_%7BC%7D%20%3D%20%5Cfrac%7B%5B%20C%5E%7Bc%7D%20%5D%7D%7B%5B%20A%5E%7Ba%7D%20%5D%5B%20B%5E%7Bb%7D%20%5D%7D%20)
Hence, Kc could vary depending on the stoichiometric coefficients of the reaction.
Answer:
The answer to the question is
The pressure of carbon dioxide after equilibrium is reached the second time is 0.27 atm rounded to 2 significant digits
Explanation:
To solve the question, we note that the mole ratio of the constituent is proportional to their partial pressure
At the first trial the mixture contains
3.6 atm CO
1.2 atm H₂O (g)
Total pressure = 3.6+1.2= 4.8 atm
which gives
3.36 atm CO
0.96 atm H₂O (g)
0.24 atm H₂ (g)
That is
CO+H₂O→CO(g)+H₂ (g)
therefore the mixture contained
0.24 atm CO₂ and the total pressure =
3.36+0.96+0.24+0.24 = 4.8 atm
when an extra 1.8 atm of CO is added we get Increase in the mole fraction of CO we have one mole of CO produces one mole of H₂
At equilibrium we have 0.24*0.24/(3.36*0.96) = 0.017857
adding 1.8 atm CO gives 4.46 atm hence we have
(0.24+x)(0.24+x)/(4.46-x)(0.96-x) = 0.017857
which gives x = 0.031 atm or x = -0.6183 atm
Dealing with only the positive values we have the pressure of carbon dioxide = 0.24+0.03 = 0.27 atm
There are 4 significant figures(3050)
All other elements react with other elements to form compounds. In the special case where the reaction produces fixed numbers of the same types of atoms in exactly the same configuration, we say the elements have formed a molecule.