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2 years ago

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Two electrons are found in the same atom. One electron has the quantum number set (4, 1, 0, +½), and the other electron has the

quantum number set (4, 1, 1, +½). They share the

1 answer:

Kruka [31]2 years ago

5 0

Quantum states of electrons are usually written in terms of four numbers: the principle quantum number (n), the angular momentum azimuthal number (L), the magnetic quantum number (ml), and the spin projection number (ms). The quantum number set (4,1,0,+1/2) and (4,1,1,+1/2) share the same principle quantum numbers and therefore both sit in the n=4 electron shell.

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A solution contains 0.0440 M Ca2 and 0.0940 M Ag. If solid Na3PO4 is added to this mixture, which of the phosphate species would

Olenka [21]

Answer:

C. $Ca_3(PO_4)_2$ will precipitate out first

the percentage of $Ca^{2+}$ remaining = 12.86%

Explanation:

Given that:

A solution contains:

$[Ca^{2+}] = 0.0440 \ M$

$[Ag^+] = 0.0940 \ M$

From the list of options , Let find the dissociation of $Ag_3PO_4$

$Ag_3PO_4 \to Ag^{3+} + PO_4^{3-}$

where;

Solubility product constant Ksp of $Ag_3PO_4$ is $8.89 \times 10^{-17}$

Thus;

$Ksp = [Ag^+]^3[PO_4^{3-}]$

replacing the known values in order to determine the unknown ; we have :

$8.89 \times 10 ^{-17} = (0.0940)^3[PO_4^{3-}]$

$\dfrac{8.89 \times 10 ^{-17}}{(0.0940)^3} = [PO_4^{3-}]$

$[PO_4^{3-}] =\dfrac{8.89 \times 10 ^{-17}}{(0.0940)^3}$

$[PO_4^{3-}] =1.07 \times 10^{-13}$

The dissociation of $Ca_3(PO_4)_2$

The solubility product constant of $Ca_3(PO_4)_2$ is $2.07 \times 10^{-32}$

The dissociation of $Ca_3(PO_4)_2$ is :

$Ca_3(PO_4)_2 \to 3Ca^{2+} + 2 PO_{4}^{3-}$

Thus;

$Ksp = [Ca^{2+}]^3 [PO_4^{3-}]^2$

$2.07 \times 10^{-33} = (0.0440)^3 [PO_4^{3-}]^2$

$\dfrac{2.07 \times 10^{-33} }{(0.0440)^3}= [PO_4^{3-}]^2$

$[PO_4^{3-}]^2 = \dfrac{2.07 \times 10^{-33} }{(0.0440)^3}$

$[PO_4^{3-}]^2 = 2.43 \times 10^{-29}$

$[PO_4^{3-}] = \sqrt{2.43 \times 10^{-29}$

$[PO_4^{3-}] =4.93 \times 10^{-15}$

Thus; the phosphate anion needed for precipitation is smaller i.e $4.93 \times 10^{-15}$ in $Ca_3(PO_4)_2$ than in $Ag_3PO_4$ $1.07 \times 10^{-13}$

Therefore:

$Ca_3(PO_4)_2$ will precipitate out first

To determine the concentration of $[Ca^+]$ when the second cation starts to precipitate ; we have :

$Ksp = [Ca^{2+}]^3 [PO_4^{3-}]^2$

$2.07 \times 10^{-33} = [Ca^{2+}]^3 (1.07 \times 10^{-13})^2$

$[Ca^{2+}]^3 = \dfrac{2.07 \times 10^{-33} }{(1.07 \times 10^{-13})^2}$

$[Ca^{2+}]^3 =1.808 \times 10^{-7}$

$[Ca^{2+}] =\sqrt[3]{1.808 \times 10^{-7}}$

$[Ca^{2+}] =0.00566$

This implies that when the second cation starts to precipitate ; the concentration of $[Ca^{2+}]$ in the solution is 0.00566

Therefore;

the percentage of $Ca^{2+}$ remaining = concentration remaining/initial concentration × 100%

the percentage of $Ca^{2+}$ remaining = 0.00566/0.0440 × 100%

the percentage of $Ca^{2+}$ remaining = 0.1286 × 100%

the percentage of $Ca^{2+}$ remaining = 12.86%

5 0

3 years ago

What does homogeneous mixture of elements mean

mina [271]

If a substance is not chemically pure, it is either a heterogeneous mixture or a homogeneous mixture. If its composition is uniform throughout, it is a homogeneous mixture.

8 0

2 years ago

Pls help i will mark you the brainlest

kap26 [50]

Answer:

Maintain constant velocity

8 0

2 years ago

2-butanone is converted into 3-methyl-3-hexanol using a grignard reagent prepared from 1-bromopropane and magnesium metal in thf

Andre45 [30]

Answer:

Here's what I get.

Explanation:

At the end of the reaction you will have a solution of the alcohol in THF.

The microdistillation procedure will vary, depending on the specific apparatus you are using, but here is a typical procedure.

Transfer the solution to a conical vial.
Add a boiling stone.
Attach a Hickman head (shown below) and condenser.
Place the assembly in in the appropriate hole of an aluminium block on top of a hotplate stirrer.
Begin stirring and heating at a low level so the THF (bp 63 °C) can distill slowly.
Use a Pasteur pipet to withdraw the THF as needed.
When all the THF has been removed, raise the temperature of the Al block and distill the alcohol (bp 143 °C).

7 0

3 years ago

An ionic bond generally occurs between two nonmetal atoms.<br><br> TRUE<br><br> FALSE

BaLLatris [955]

False; an ionic bond generally occurs between a nonmetal and a metal; for example, NaCl.

5 0

2 years ago