By increasing the P reaction moves toward less number of moles in this case
<span>The equilibrium will shift to the left to favor the reverse reaction.</span>
Answer: pH = 4.996
Explanation:
No of moles = molarity x volume
:• no of moles of CH3COOH = 0.1M x 0.1L
n(CH3COOH) = 0.1mol
Since 0.03mole of NaOH is added, then 0.03 mole of CH3COOH will be converted to the conjugate.
Therefore, Moles of CH3COOH becomes,
0.1 - 0.03 = 0.07 mol
Subsequently, the moles of CH3COONa increases and becomes,
0.08 + 0.03 = 0.11 mol
Using the Hendersom-Hasselbach equation,
pH = pKa + log [Moles of conjugate÷ moles of Ch3COOH]
From literature, pKa of Ch3COOH is 4.8
Thus,
pH = 4.8 + log [0.11/0.07]
pH = 4.8 + 0.1963
pH = 4.996
C seems to be the best answer
Answer:
1, 2, and 3 are true.
Explanation:
The Henderson-Hasselbalch equation is:
pH = pka + log₁₀ ![\frac{[A^-]}{[HA]}](https://tex.z-dn.net/?f=%5Cfrac%7B%5BA%5E-%5D%7D%7B%5BHA%5D%7D)
- If the pH of the solution is known as is the pKa for the acid, the ratio of conjugate base to acid can be determined. <em>TRUE</em>
pH = pka + log₁₀ ![\frac{[A^-]}{[HA]}](https://tex.z-dn.net/?f=%5Cfrac%7B%5BA%5E-%5D%7D%7B%5BHA%5D%7D)
If you know pH and pka:
10^(pH-pka) = ![\frac{[A^-]}{[HA]}](https://tex.z-dn.net/?f=%5Cfrac%7B%5BA%5E-%5D%7D%7B%5BHA%5D%7D)
The ratio will be: 10^(pH-pka)
- At pH = pKa for an acid, [conjugate base] = [acid] in solution. <em>TRUE</em>
pH = pka + log₁₀ ![\frac{[A^-]}{[HA]}](https://tex.z-dn.net/?f=%5Cfrac%7B%5BA%5E-%5D%7D%7B%5BHA%5D%7D)
0 = log₁₀ ![\frac{[A^-]}{[HA]}](https://tex.z-dn.net/?f=%5Cfrac%7B%5BA%5E-%5D%7D%7B%5BHA%5D%7D)
10^0 = ![\frac{[A^-]}{[HA]}](https://tex.z-dn.net/?f=%5Cfrac%7B%5BA%5E-%5D%7D%7B%5BHA%5D%7D)
1 = ![\frac{[A^-]}{[HA]}](https://tex.z-dn.net/?f=%5Cfrac%7B%5BA%5E-%5D%7D%7B%5BHA%5D%7D)
As ratio is 1, [conjugate base] = [acid] in solution.
- At pH >> pKa for an acid, the acid will be mostly ionized. <em>TRUE</em>
pH = pka + log₁₀ ![\frac{[A^-]}{[HA]}](https://tex.z-dn.net/?f=%5Cfrac%7B%5BA%5E-%5D%7D%7B%5BHA%5D%7D)
If pH >> pKa, 10^(pH-pka) will be >> 1, that means that you have more [A⁻] than [HA]
- At pH << pKa for an acid, the acid will be mostly ionized. <em>FALSE</em>
pH = pka + log₁₀ ![\frac{[A^-]}{[HA]}](https://tex.z-dn.net/?f=%5Cfrac%7B%5BA%5E-%5D%7D%7B%5BHA%5D%7D)
If pH << pKa, 10^(pH-pka) will be << 1, that means that you have more [HA] than [A⁻]
I hope it helps!