Question

Determine the standard enthalpy of formation in kJ/mol for NO given the following information about the formation of NO2 under standard conditions, and (NO2) = + 33.2 kJ/mol. Keep one decimal point. 2 NO(g) + O2(g) → 2 NO2(g) ∆Hrxn = –114.2 kJ

Answer 1

Answer:

90.3 kJ/mol

Explanation:

Let's consider the following thermochemical equation.

2 NO(g) + O₂(g) → 2 NO₂(g)  ∆H°rxn = –114.2 kJ

We can find the standard enthalpy of formation for NO using the following expression.

∆H°rxn = 2 mol × ΔH°f(NO₂(g)) - 2 mol × ΔH°f(NO(g)) - 1 mol × ΔH°f(O₂(g))

∆H°rxn = 2 mol × ΔH°f(NO₂(g)) - 2 mol × ΔH°f(NO(g)) - 1 mol × 0 kJ/mol

∆H°rxn = 2 mol × ΔH°f(NO₂(g)) - 2 mol × ΔH°f(NO(g))

ΔH°f(NO(g)) = (2 mol × ΔH°f(NO₂(g)) - ∆H°rxn) / 2 mol

ΔH°f(NO(g)) = (2 mol × 33.2 kJ/mol + 114.2 kJ) / 2 mol

ΔH°f(NO(g)) = 90.3 kJ/mol