Given reaction represents dissociation of bromine gas to form bromine atoms
Br2(g) ↔ 2Br(g)
The enthalpy of the above reaction is given as:
ΔH = ∑n(products)Δ
- ∑n(reactants)Δ
where n = number of moles
Δ
= enthalpy of formation
ΔH = [2*ΔH(Br(g)) - ΔH(Br2(g))] = 2*111.9 - 30.9 = 192.9 kJ/mol
Thus, enthalpy of dissociation is the bond energy of Br-Br = 192.9 kJ/mol
The water reaches its boiling point and turns into water vapor. This process is a physical change. The change is substance status. And the physical change will not destroy the molecular structure. So the molecular structure will not change.