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Charra [1.4K]
3 years ago
12

What are some possible sources of error in a titration experiment? Share some tips to minimize errors with your classmates.

Chemistry
2 answers:
NNADVOKAT [17]3 years ago
8 0

Answer:

1. by not avoiding air bubbles from being trapped in the burette or pipette when filling them

2. not cross-checking the burette if it's slanted or vertically clamped

3. forgetting to rinse the pipette or burette with the solution to be used

4. not considering to take readings from the bottom of the meniscus with the eye level

5. finally, adding more than three drops of indicators to the pipetted solution

Explanation:

1. because the air bubbles will be mistakenly considered as part of the amount of the solution taken instead of that actually used up, and a higher titre value would be obtained

2. because if it's slanted, the acid level will be titled to one side and wrong reading will be recorded

3. rinsing to avoid diluting the acid or base with water that wets the burette or pipette

4. to avoid error of parallax and helps you to obtain accurate readings

5. excess burette solution than would normally have been consumed would be used up to change the colour of the indicator

Inessa [10]3 years ago
8 0
Yhhhh bjejebejdjbd Nd djbdjxj dbduncbxjdj
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When you combine 50.0 mL of 0.100 M AgNO3 with 50.0 mL of 0.100 M HCl in a coffee-cup calorimeter, the temperature changes from
RideAnS [48]

Answer : The enthalpy of reaction (\Delta H_{rxn}) is, 67.716 KJ/mole

Explanation :

First we have to calculate the moles of AgNO_3 and HCl.

\text{Moles of }AgNO_3=\text{Molarity of }AgNO_3\times \text{Volume}=(0.100mole/L)\times (0.05L)=0.005mole

\text{Moles of }HCl=\text{Molarity of }HCl\times \text{Volume}=(0.100mole/L)\times (0.05L)=0.005mole

Now we have to calculate the moles of AgCl formed.

The balanced chemical reaction will be,

AgNO_3(aq)+HCl(aq)\rightarrow AgCl(s)+HNO_3(aq)

As, 1 mole of AgNO_3 react with 1 mole of HCl to give 1 mole of AgCl

So, 0.005 mole of AgNO_3 react with 0.005 mole of HCl to give 1 mole of AgCl

The moles of AgCl formed  = 0.005 mole

Total volume of the solution = 50.0 ml + 50.0 ml = 100.0 ml

Now we have to calculate the mass of solution.

Mass of the solution = Density of the solution × Volume of the solution

Mass of the solution = 1.00 g/ml × 100.0 ml = 100 g

Now we have to calculate the heat.

q=m\times C\Delta T=m\times C \times (T_2-T_1)

where,

q = heat

C = specific heat capacity = 4.18J/g^oC

m = mass = 100 g

T_2 = final temperature = 24.21^oC

T_1 = initial temperature = 23.40^oC

Now put all the given values in the above expression, we get:

q=100g\times (4.18J/g^oC)\times (24.21-23.40)^oC

q=338.58J

Now  we have to calculate the enthalpy of the reaction.

\Delta H_{rxn}=\frac{q}{n}

where,

\Delta H_{rxn} = enthalpy of reaction = ?

q = heat of reaction = 338.58 J

n = moles of reaction = 0.005 mole

Now put all the given values in above expression, we get:

\Delta H_{rxn}=\frac{338.58J}{0.005mole}=6771.6J/mole=67.716KJ/mole

Conversion used : (1 KJ = 1000 J)

Therefore, the enthalpy of reaction (\Delta H_{rxn}) is, 67.716 KJ/mole

4 0
3 years ago
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