Answer:
The volume is 13, 69 L
Explanation:
We use the formula PV=nRT. We convert the temperature in Celsius into Kelvin and the pressure in mmHg into atm.
0°C= 273K---> 56°C= 56 + 273= 329K
760 mmHg----1 atm
719 mmHg----x= (719 mmHgx 1 atm)/760 mmHg= 0,95 atm
PV=nRT ---> V= (nRT)/P
V=( 0,482 molx 0,082 l atm/K mol x 329K)/0,95 atm
<em>V=13,68778526 L</em>
<span>Answer is: pH of solution of sodium cyanide is 11.3.
Chemical reaction 1: NaCN(aq) → CN</span>⁻(aq)
+ Na⁺<span>(aq).
Chemical reaction 2: CN</span>⁻ +
H₂O(l) ⇄ HCN(aq) + OH⁻<span>(aq).
c(NaCN) = c(CN</span>⁻<span>)
= 0.021 M.
Ka(HCN) = 4.9·10</span>⁻¹⁰<span>.
Kb(CN</span>⁻) = 10⁻¹⁴ ÷
4.9·10⁻¹⁰ = 2.04·10⁻⁵<span>.
Kb = [HCN] · [OH</span>⁻]
/ [CN⁻<span>].
[HCN] · [OH</span>⁻<span>] =
x.
[CN</span>⁻<span>] = 0.021 M - x..
2.04·10</span>⁻⁵<span> = x² / (0.021 M
- x).
Solve quadratic equation: x = [OH</span>⁻<span>] = 0.00198 M.
pOH = -log(0.00198 M) = 2.70.
pH = 14 - 2.70 = 11.3.</span>
Use the universal gas formula
PV=nRT
where
P=pressure ( 0.980 atm)
V=volume (L)
T=temperature ( 23 ° C = 23+273.15 = 296.15 ° K)
n=number of moles of ideal gas (0.485 mol)
R=universal gas constant = 0.08205 L atm / (mol·K)
Substitute values,
Volume, V (in litres)
=nRT/P
=0.485*0.08205*296.15/0.980
= 12.0256 L
= 12.0 L (to three significant figures)
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