Given:
K = 0.71 = Kp
The reaction of sulphur with oxygen is
S(s) + O2(g) ---> SO2(g)
initial Pressure 6.90 0
Change -x +x
Equilibrium 6.90-x x
Kp = pSO2 / pO2 = 0.71 = x / (6.90-x)
4.899 - 0.71x = x
4.899 = 1.71x
x = 2.86 atm = pressure of SO2 formed
temperature = 950 C = 950 + 273.15 K = 1223.15 K
Volume = 50 L
Let us calculate moles of SO2 formed using ideal gas equation as
PV = nRT
R = gas constant = 0.0821 L atm / mol K
putting other values
n = PV / RT = 2.86 X 50 / 1223.15 X 0.0821 = 1.42 moles
Moles of Sulphur required = 1.42 moles
Mass of sulphur required or consumed = moles X atomic mass of sulphur
mass of S = 1.42 X 32 = 45.57 grams or 0.04557 Kg of sulphur
None. Both chlorines and both hydrogens are single-bonded to the central carbon atom; the molecule is comprised of four single bonds and no double bonds.
Hope this helps!
Volume of tank = 
(given)
Since, 
So,
For :
The significant rule for multiplication, states that the number of significant figures in the answer obtained by multiplication is determined by the value with the lowest number of significant digits.
Since, the minimum number of decimal places in the above multiplication operation is 1 so, the final result must be upto 1 decimal place only.
Hence, volume in 
is 243.5.
