Freezing point depression depends of the number of particles of the solute in the solution.
1)Pure water have highest freezing point. All other solutions with given solutes will have lower temperatures.
2) The more particles of the solute in the solution the lower freezing point is going to be.
<span>b. 1.0 m NaCl ( dissociates and give 2 mol ions (1 mol Na⁺ and 1 mol Cl⁻))
c. 1.0 m K3PO4 (</span>dissociates and give 4 mol ions (3 mol K⁺ and 1 mol PO4³⁻)<span>
d. 1.0 m CaCl2 (</span>dissociates and give 3 mol ions (1 mol Ca²⁺ and 2 mol Cl⁻))<span>
e. 1.0 m glucose (c6h12o6) (glucose does not dissociate, and solution have
1 mole of particles of the solute(glucose))
The largest number of particles has </span>1.0 m K3PO4 solution, and it is has lowest freezing point . Answer is C.
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Answer : The pH of the solution is, 9.63
Explanation : Given,
The dissociation constant for HCN = 
First we have to calculate the moles of HCN and NaCN.

and,

The balanced chemical reaction is:

Initial moles 0.1116 0.0461 0.08978
At eqm. (0.1116-0.0461) 0 (0.08978+0.0461)
0.0655 0.1359
Now we have to calculate the pH of the solution.
Using Henderson Hesselbach equation :
![pH=pK_a+\log \frac{[Salt]}{[Acid]}](https://tex.z-dn.net/?f=pH%3DpK_a%2B%5Clog%20%5Cfrac%7B%5BSalt%5D%7D%7B%5BAcid%5D%7D)
Now put all the given values in this expression, we get:


Therefore, the pH of the solution is, 9.63
Explanation:
an acid will give away a proton and become a conjugate base.
A base will accept a proton and become a conjugate acid.