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EastWind [94]
3 years ago
9

Determine the expected diffraction angle for the first-order diffraction from the (111) set of planes for FCC nickel (Ni) when m

onochromatic radiation of wavelength 0.1937 nm is used. The lattice parameter for Ni is 0.3524 nm
Chemistry
1 answer:
faust18 [17]3 years ago
4 0

Answer:

56°

Explanation:

First calculate a:

a=2 R \sqrt{2}=2(0.1246) \sqrt{2}=0.352 \mathrm{nm}

The interplanar spacing can be calculated from:

d_{111}=\frac{a}{\sqrt{1^{2}+1^{2}+1^{2}}}=\frac{0.352}{\sqrt{3}}=0.203 \mathrm{nm}

The diffraction angle is determined from:

\sin \theta=\frac{n \lambda}{2 d_{111}}=\frac{1(0.1927)}{2(0.2035)}=0.476

Solve for \theta

\theta=\sin ^{-1}(0.476)=28^{\circ}

The diffraction angle is:

2 \theta=2\left(28^{\circ}\right)=56^{\circ}

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In acidic aqueous solution, the purple complex ion Co(NH3)5Br2+ undergoes a slow reaction in which the bromide ion is replaced b
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Answer:

A) 0.065 M is its molarity after a reaction time of 19.0 hour.

B) In 52 hours [Co(NH_3)5Br]^{2+} will react 69% of its initial concentration.

Explanation:

Co(NH_3)_5(H_2O)_3+[Co(NH_3)5Br]^{2+}(Purple)(aq)+H_2O(l)\rightarrow [Co(NH_3)_5(H_2O)]^{3+}(Pinkish-orange)(aq)+Br^-(aq)

The reaction is first order in [Co(NH_3)5Br]^{2+}:

Initial concentration of [Co(NH_3)5Br]^{2+}= [A_o]=0.100 M

a) Final concentration of [Co(NH_3)5Br]^{2+} after 19.0 hours= [A]

t = 19.0 hour = 19.0 × 3600 seconds ( 1 hour = 3600 seconds)

Rate constant of the reaction = k = 6.3\times 10^{-6} s^{-1}

The integrated law of first order kinetic is given as:

[A]=[A_o]\times e^{-kt}

[A]=0.100 M\times e^{-6.3\times 10^{-6} s^{-1}\times 19.0\times 3600 s}

[A]=0.065 M

0.065 M is its molarity after a reaction time of 19.0 h.

b)

Initial concentration of [Co(NH_3)5Br]^{2+}= [A_o]=x

Final concentration of [Co(NH_3)5Br]^{2+} after t = [A]=(100\%-69\%) x=31\%x=0.31x

Rate constant of the reaction = k = 6.3\times 10^{-6} s^{-1}

The integrated law of first order kinetic is given as:

[A]=[A_o]\times e^{-kt}

0.31x=x\times e^{-6.3\times 10^{-6} s^{-1}\t}

t = 185,902.06 s = \frac{185,902.06 }{3600} hour = 51.64 hours ≈ 52 hours

In 52 hours [Co(NH_3)5Br]^{2+} will react 69% of its initial concentration.

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