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Aleonysh [2.5K]
3 years ago
10

25 POINTS

Chemistry
1 answer:
Oliga [24]3 years ago
6 0

Answer:

Assuming that O₂ is the limiting reagent, approximately 1.6 liters of NO will be produced.

Explanation:

Make sure that the equation has been balanced.

The coefficient in front of \rm NO is 4; the coefficient in front of \rm O_2 is 5. The ratio between these two coefficients is equal to \displaystyle \frac{4}{5} = 0.8.

Assume that \rm O_2 is indeed the limiting reagent. In other words, assume that \rm O_2 runs out before all \rm NH_3 is consumed. The ratio between the number of moles of \rm NO produced and the number of moles of \rm O_2 consumed will also be equal to 0.8. That is:

\displaystyle \frac{n(\mathrm{NO})}{n(\mathrm{O_2})} = \frac{\text{Coefficient of $\mathrm{NO}$}}{\text{Coefficient of $\mathrm{O_2}$}} = 0.8.

Additionally, both \rm NO and \rm O_2 are gases. Under the same temperature and pressure, one mole of each gas would occupy about the same volume. As a result,

\displaystyle \frac{V(\mathrm{NO})}{V(\mathrm{O_2})} = \frac{n(\mathrm{NO})}{n(\mathrm{O_2})} = 0.8.

The volume of \rm O_2 is already known. Hence, the volume of \rm NO produced will be equal to:

\begin{aligned} V(\mathrm{NO}) &= \frac{V(\mathrm{NO})}{V(\mathrm{O_2})} \cdot V(\mathrm{O_2}) \cr &= 0.8 \times (2.0\; \rm L) \cr &= \rm 1.6\; L\end{aligned}.

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What is the vapor pressure of the solution if 35.0 g of water is dissolved in 100.0 g of ethyl alcohol at 25 ∘C? The vapor press
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<u>Answer:</u> The vapor pressure of the solution is 43.55 mmHg

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To calculate the number of moles, we use the equation:

\text{Number of moles}=\frac{\text{Given mass}}{\text{Molar mass}}      .....(1)

  • <u>For water:</u>

Given mass of water = 35.0 g

Molar mass of water = 18 g/mol

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Given mass of ethyl alcohol = 100.0 g

Molar mass of ethyl alcohol = 46 g/mol

Putting values in equation 1, we get:

\text{Moles of ethyl alcohol}=\frac{100.0g}{46g/mol}=2.174mol

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  • Mole fraction of a substance is given by:

\chi_A=\frac{n_A}{n_A+n_B}

<u>For water:</u>

\chi_{\text{water}}=\frac{n_{\text{water}}}{n_{\text{water}}+n_{\text{ethyl alcohol}}}

\chi_{water}=\frac{1.944}{4.118}=0.472

<u>For ethyl alcohol:</u>

\chi_{\text{ethyl alcohol}}=\frac{n_{\text{ethyl alcohol}}}{n_{\text{water}}+n_{\text{ethyl alcohol}}}

\chi_{\text{ethyl alcohol}}=\frac{2.174}{4.118}=0.528

Dalton's law of partial pressure states that the total pressure of the system is equal to the sum of partial pressure of each component present in it.

To calculate the vapor pressure of the solution, we use the law given by Dalton, which is:

P_T=\sum_{i=1}^n (p_i\times \chi_i)

Or,

P_T=[(p_{\text{water}}\times \chi_{\text{water}})+(p_{\text{ethyl alcohol}}\times \chi_{\text{ethyl alcohol}}

We are given:

Vapor pressure of water = 23.8 mmHg

Vapor pressure of ethyl alcohol = 61.2 mmHg

Putting values in above equation, we get:

p_T=[(23.8\times 0.472)+(61.2\times 0.528)]\\\\p_T=43.55mmHg

Hence, the vapor pressure of the solution is 43.55 mmHg

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