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ludmilkaskok [199]
2 years ago
12

Cis-4-tertButylcyclohexyl bromide (compound 1) and Trans-4 tert Butylcyclohexylbromide (compound 2) are reacted with Potassium T

ertiary butoxide in Tertiary butanol to produce 4-tertbutylcyclohexene. The following statement is completely true?A. In compound 1 the Tert butyl group occupies the equatorial position and the Bromine occupies the axial position and in compound 2 both the Tert butyl and the bromine occupy equatorial positions. Compound 1 reacts faster than compound 2.
B. In compound 1 the Tert butyl group occupies the axial position and the Bromine occupies the axial position and in compound 2 both the Tert butyl and the bromine occupy equatorial positions. Compound 1 reacts faster than compound 2.
C. In compound 1 the Tert butyl group occupies the equatorial position and the Bromine occupies the equatorial position and in compound 2 both the Tert butyl and the bromine occupy equatorial positions. Compound 1 reacts faster than compound 2.
D. In compound 1 the Tert butyl group occupies the equatorial position and the Bromine occupies the axial position and in compound 2 the Tert butyl occupies the axial and the bromine occupies equatorial positions. Compound 1 reacts faster than compound 2.
E. In compound 1 the Tert butyl group occupies the equatorial position and the Bromine occupies the axial position and in compound 2 both the Tert butyl occupies the equatorial and the bromine occupies axial position. Compound 1 reacts faster than compound 2.
F. In compound 1 the Tert butyl group occupies the equatorial position and the Bromine occupies the axial position and in compound 2 both the Tert butyl and the bromine occupy equatorial positions. Compond 2 reacts faster than compound 1.
Chemistry
1 answer:
Mkey [24]2 years ago
4 0

Answer:

In compound 1 the Tert butyl group occupies the equatorial position and the Bromine occupies the axial position and in compound 2 the Tert butyl occupies the axial and the bromine occupies equatorial positions. Compound 1 reacts faster than compound 2.

Explanation:

In cyclic organic compounds, substituents may occupy the axial or equatorial positions. The axial positions are aligned parallel to the symmetry axis of the ring while the equatorial positions are around the plane of the ring.

Bulky substituents have more room in the equatorial than in the axial position. This means that compound 1 is more stable than compound 2.

This is clear on the basis of stability of the molecules because compound 1 will react faster than compound 2 since the bulky tertiary butyl group in compound 1 occupy equatorial and not axial positions.

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Answer:

N₂  = 6.022 × 10²³ molecules

H₂ = 18.066 × 10²³ molecules

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Explanation:

Chemical equation;

N₂ + 3H₂     →  2NH₃

It can be seen that there are one mole of nitrogen three mole of hydrogen and two moles of ammonia are present in this equation. The number of molecules of reactant and product would be calculated by using Avogadro number.

The given problem will solve by using Avogadro number.

It is the number of atoms , ions and molecules in one gram atom of element, one gram molecules of compound and one gram ions of a substance.

The number 6.022 × 10²³ is called Avogadro number.

For example,

Number of molecules of nitrogen gas:

1 mol = 6.022 × 10²³ molecules

Number of molecules of hydrogen:

3 mol × 6.022 × 10²³ molecules/ 1 mol

18.066 × 10²³ molecules

Number of molecules of ammonia:

2 mol × 6.022 × 10²³ molecules/ 1 mol

12.044 × 10²³ molecules

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Thus, aluminium cation consist of few electrons which results in fewer occupied energy levels by the electrons further results in reduction of radius i.e. smaller size.

Hence, given statement is true i.e. aluminium atom is larger than the aluminium cation as cation has fewer occupied energy levels.



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