Answer:
V is proportional to StartFraction n over p EndFraction.
Explanation:
Let us remind ourselves of the statements of both Boyle's law and Avogadro's laws.
Boyle's law states that, the volume of a given mass of gas is inversely proportional to its pressure at constant temperature.
Avogadro's law states that at the same temperature and pressure, equal volumes of gases contain equal number of molecules.
Hence ;
V α 1/P (Boyle's law)
V α n (Avogadro's law)
V α n/p (combination of Boyle's law and Avogadro's law)
Answer:
The correct order of increasing reactivity toward nucleophilic acyl substitution is E < D < C < A < F < B.
Explanation:
The stability of the leaving group best determines the manner of reactivity of carboxylates to nucleophilic substitution after the substitution of the nucleophile to the leaving group. The leaving group should, therefore, be protonated with hydrogen ion in the solution to form a stable molecule. From the given list: The leaving group for A, Ethyl thioacetate will be ethanethiol. For B, Acetyl chloride will be Hydrochloric acid. For C, Sodium acetate will be Sodium Hydroxide. For D, Ethyl acetate will be Ethanol. For E, Acetamide will be Ammonia, and for F, Acetic anhydride will be Ethanoic acid. The reactivity of the substitution reaction is dependent on the stability of these leaving groups. The stability of these leaving groups depends on their pKa, and the more the pKa, the lesser the acidity of the leaving group, and the lower the reactivity. Therefore, considering their pKa: A is 8.5, B is -7, C is 13.8, D is 15.9, E is 36, and F is 4.8. When we rearrange this pKa in descending order, we have E, D. C, A, F, B. Which is also the increased reactivity of the nucleophilic acyl substitution.
Answer:
evaporation or water runoff that's my tips
rain or thunder storm
C. Spacecraft are built to be airtight.