In non-polar covalent bonds, the electrons are equally shared between the two atoms. For atoms with differing electronegativity, the bond will be a polar covalent interaction, where the electrons will not be shared equally.
The reaction of HCl and NaOH is HCl + NaOH = NaCl + H2O. So the mole number of HCl and NaOH is equal. So the volume of HCl =0.01*0.1/0.02=0.05 L =50 ml. So the answer is D).