Answer:
Explanation:
*Since the titration is between the strong acid HCl and the strong base Ca(OH)2, the pH at the equivalent point should be 7. On interpolation, we will obtain that 9.50mL and 9.82 mL of HCl is required to completely neutralized the given Ca(OH)2 solution.
*pH at the equivalence point =7
we know that pH + pOH = 14
Hence pOH= 14-7=7
pOH= -log(OH-)
The concentration of OH-= 10-pH= 1X10-7 M
One reason for the low solubility may be the higher reaction temperature, Another reason is the common ion effect.
Answer:
D
Explanation:
If the deer leave the forest then they are avoiding compotation
Hydrogen Peroxide slowly decomposing into water and oxygen increases the entropy of the universe. Any reaction of a system always increases the degree of the orderliness of the universe. Decomposition is one of the best examples of increasing the entropy. This is when substance is broken down further to elements or other compounds.
The question is incomplete, here is the complete question:
The rate constant of a certain reaction is known to obey the Arrhenius equation, and to have an activation energy Ea = 71.0 kJ/mol . If the rate constant of this reaction is 6.7 M^(-1)*s^(-1) at 244.0 degrees Celsius, what will the rate constant be at 324.0 degrees Celsius?
<u>Answer:</u> The rate constant at 324°C is 
<u>Explanation:</u>
To calculate rate constant at two different temperatures of the reaction, we use Arrhenius equation, which is:
![\ln(\frac{K_{324^oC}}{K_{244^oC}})=\frac{E_a}{R}[\frac{1}{T_1}-\frac{1}{T_2}]](https://tex.z-dn.net/?f=%5Cln%28%5Cfrac%7BK_%7B324%5EoC%7D%7D%7BK_%7B244%5EoC%7D%7D%29%3D%5Cfrac%7BE_a%7D%7BR%7D%5B%5Cfrac%7B1%7D%7BT_1%7D-%5Cfrac%7B1%7D%7BT_2%7D%5D)
where,
= equilibrium constant at 244°C = 
= equilibrium constant at 324°C = ?
= Activation energy = 71.0 kJ/mol = 71000 J/mol (Conversion factor: 1 kJ = 1000 J)
R = Gas constant = 8.314 J/mol K
= initial temperature = ![244^oC=[273+244]K=517K](https://tex.z-dn.net/?f=244%5EoC%3D%5B273%2B244%5DK%3D517K)
= final temperature = ![324^oC=[273+324]K=597K](https://tex.z-dn.net/?f=324%5EoC%3D%5B273%2B324%5DK%3D597K)
Putting values in above equation, we get:
![\ln(\frac{K_{324^oC}}{6.7})=\frac{71000J}{8.314J/mol.K}[\frac{1}{517}-\frac{1}{597}]\\\\K_{324^oC}=61.29M^{-1}s^{-1}](https://tex.z-dn.net/?f=%5Cln%28%5Cfrac%7BK_%7B324%5EoC%7D%7D%7B6.7%7D%29%3D%5Cfrac%7B71000J%7D%7B8.314J%2Fmol.K%7D%5B%5Cfrac%7B1%7D%7B517%7D-%5Cfrac%7B1%7D%7B597%7D%5D%5C%5C%5C%5CK_%7B324%5EoC%7D%3D61.29M%5E%7B-1%7Ds%5E%7B-1%7D)
Hence, the rate constant at 324°C is
This question is testing to see how well you understand the "half-life" of radioactive elements, and how well you can manipulate and dance around them. This is not an easy question.
The idea is that the "half-life" is a certain amount of time. It's the time it takes for 'half' of the atoms in any sample of that particular unstable element to 'decay' ... their nuclei die, fall apart, and turn into nuclei of other elements.
Look over the table. There are 4,500 atoms of this radioactive substance when the time is 12,000 seconds, and there are 2,250 atoms of it left when the time is ' y ' seconds. Gosh ... 2,250 is exactly half of 4,500 ! So the length of time from 12,000 seconds until ' y ' is the half life of this substance ! But how can we find the length of the half-life ? ? ?
Maybe we can figure it out from other information in the table !
Here's what I found:
Do you see the time when there were 3,600 atoms of it ?
That's 20,000 seconds.
... After one half-life, there were 1,800 atoms left.
... After another half-life, there were 900 atoms left.
... After another half-life, there were 450 atoms left.
==> 450 is in the table ! That's at 95,000 seconds.
So the length of time from 20,000 seconds until 95,000 seconds
is three half-lifes.
The length of time is (95,000 - 20,000) = 75,000 sec
3 half lifes = 75,000 sec
Divide each side by 3 : 1 half life = 25,000 seconds
There it is ! THAT's the number we need. We can answer the question now.
==> 2,250 atoms is half of 4,500 atoms.
==> ' y ' is one half-life later than 12,000 seconds
==> ' y ' = 12,000 + 25,000
y = 37,000 seconds .
Check:
Look how nicely 37,000sec fits in between 20,000 and 60,000 in the table.
As I said earlier, this is not the simplest half-life problem I've seen.
You really have to know what you're doing on this one. You can't
bluff through it.
