Answer:
a) 
b) 
Explanation:
Equation of reaction:

Initial pressure 3 1 0
Pressure change 2P 1P 2P
Total pressure = (3-2P) + (1-P) + (2P)
Total Pressure = 3.75 atm
(3-2P) + (1-P) + (2P) = 3.75
4 - P = 3.75
P = 4 - 3.75
P = 0.25 atm
Let us calculate the pressure of each of the components of the reaction:
Pressure of XO2 = 3 - 2P = 3 - 2(0.25)
Pressure of XO2 =2.5 atm
Pressure of O2 = 1 - P = 1 -0.25
Pressure of O2 = 0.75 atm
Pressure of XO3 = 2P = 2 * 0.25
Pressure of XO3 = 0.5 atm
From the reaction, equilibrium constant can be calculated using the formula:
![K_{p} = \frac{[PXO_{3}] ^{2} }{[PXO_{2}] ^{2}[PO_{2}] }](https://tex.z-dn.net/?f=K_%7Bp%7D%20%3D%20%5Cfrac%7B%5BPXO_%7B3%7D%5D%20%5E%7B2%7D%20%7D%7B%5BPXO_%7B2%7D%5D%20%5E%7B2%7D%5BPO_%7B2%7D%5D%20%7D)

Standard free energy:

b) value of k−1 at 27 °C, i.e. 300K



Answer:
Decreases
Explanation:
The atmospheric pressure on the surface of the mercury pushes it up the evacuated tube until the downward pressure of the mercury equals the atmospheric pressure.
If the atmospheric pressure decreases, the mercury doesn't have to rise as high.
The mercury height decreases.
The average atomic mass of N2 is 14.0067. The atomic masses of the 2 stable isotopes of nitrogen, N-14 and N-15, are14.003074002 and 15.00010897 amu, respectively. Calculate the percent abundance of each nitrogen isotope. Ex.: The average atomic weight of copper is 63.5amu .
hope this helps!!!
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