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ELEN [110]
3 years ago
13

A piston confines 0.200 mol Ne(g) in 1.20 at 25 degree C. Two experiments are performed. (a) The gas is allowed to expand throug

h an additional 1.20 L against a constant of 1.00atm. (b) The gas is allowed to expand reversibly and isothermally to the same final volume. Please calculate the work done by the gas system in these two processes, respectively. Which process does more work? (revised from 6/e exercise 8.11) Please show calculation details.
Chemistry
1 answer:
djyliett [7]3 years ago
7 0

Answer:

The second experiment (reversible path) does more work

Explanation:

Step 1:

A piston confines 0.200 mol Ne(g) in 1.20L at 25 degree °C

<em>(a) The gas is allowed to expand through an additional 1.20 L against a constant of 1.00atm</em>

<em></em>

Irreversible path: w =-Pex*ΔV

⇒ with Pex = 1.00 atm

⇒ with ΔV = 1.20 L

W = -(1.00 atm) * 1.20 L

W = -1.20L*atm *101.325 J /1 L*atm = -121.59 J

<em>(b) The gas is allowed to expand reversibly and isothermally to the same final volume.</em>

<em></em>

W = -nRTln(Vfinal/Vinitial)

⇒ with n = the number of moles = 0.200

⇒ with R = gas constant = 8.3145 J/K*mol

⇒ with T = 298 Kelvin

⇒ with Vfinal/Vinitial  = 2.40/1.20 = 2

W = -(0.200mol) * 8.3145 J/K*mol *298K *ln(2.4/1.2)

W = -343.5 J

The second experiment (reversible path) does more work

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ryzh [129]

Answer:

Conformational  isomers

Explanation:

Conformational isomers are temporarily different shapes of the same molecule and for this reason are not classified as isomers in some textbooks.

7 0
3 years ago
A student combines 364.6 g of HCl with 80 g of NaOH in 5 L of water. What additional volume of H2O must be added to this mixture
Jobisdone [24]

Answer:

75L of additional water to have a pH 1 solution

Explanation:

The reaction of HCl With NaOH is:

HCl + NaOH → H₂O + NaCl

By using molar mass of each reactant you can know how many moles will react, thus:

HCl: 364.6g HCl ₓ (1mol / 36.46g) = 10 moles HCl

NaOH: 80g NaOH ₓ (1mol / 40g) = 2 moles NaOH

That means after the reaction will remain in solution, 10-2 = 8 moles of HCl = 8 moles of H⁺ (In water, HCl dissociates as H⁺ and Cl⁻ ions).

A solution with pH = 1 contains:

pH = -log [H⁺]

1 = -log [H⁺]

0.1M = [H⁺]

As molarity, M is the ratio between moles and liters and you want a solution 0.1M having 8 moles of H⁺ you require:

0.1M = 8 moles H⁺ / 80L

As the student combines the solution with 5L of water, you require

<h3>75L of additional water to have a pH 1 solution</h3>
6 0
3 years ago
The color of light emitted during a flame test depends on
tiny-mole [99]

option of d is the write answer

3 0
3 years ago
Read 2 more answers
What is the total pressure in atmospheres in a 10.0L vessel containing 2.50 x 10-3 mol H2, 1.00 x 10-3
grigory [225]

Answer:

Total pressure = 16.42× 10⁻⁹atm

Explanation:

Given data:

Moles of H₂ = 2.50 × 10⁻³ mol

Moles of He = 1.00 × 10⁻³ mol

Mass of Ne = 3 × 10⁻⁴ mol

Volume = 10 L

Temperature = 35°C

Total pressure = ?

Solution:

Pressure of hydrogen:

P = nRT / V

P = 2.50 × 10⁻³ mol× 0.0821 atm. L.mol⁻¹ .k⁻¹ × 308 K / 10 L

p = 63.22× 10⁻³  atm. L /10 L

P = 6.3 × 10⁻³atm

Pressure of helium:

P = nRT / V

P = 1.00 × 10⁻³ mol× 0.0821 atm. L.mol⁻¹ .k⁻¹ × 308 K / 10 L

p = 25.29 × 10⁻³ atm. L /10 L

P = 2.53× 10⁻³ atm

Pressure of neon:

P = nRT / V

P = 3 × 10⁻⁴ mol× 0.0821 atm. L.mol⁻¹ .k⁻¹ × 308 K / 10 L

p = 75.86× 10⁻³ atm. L /10 L

P = 7.59× 10⁻³ atm

Total pressure of mixture:

P(mixture)  = pressure of hydrogen + pressure of helium+ pressure of neon

P(mixture)  = 6.3 × 10⁻³atm + 2.53× 10⁻³ atm + 7.59× 10⁻³ atm

P(mixture) = 16.42× 10⁻⁹atm

8 0
3 years ago
Write the balanced equation for the formation of carbon dioxide.
ohaa [14]
C + O2 ——> CO2
Carbon plus oxygen forms carbon dioxide
4 0
3 years ago
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