Answer : The correct option is, (B) 273.15 K and 1 atm
Explanation :
STP : STP stands for standard temperature and pressure.
STP conditions :
The temperature is, or
or
The pressure is, or
The volume is 22.4 L for 1 mole of a substance.
Hence, the correct option is, (B) 273.15 K and 1 atm
Answer:
Ea = 177x10³ J/mol
ko = J/mol
Explanation:
The specific reaction rate can be calculated by Arrhenius equation:
Where k0 is a constant, Ea is the activation energy, R is the gas constant, and T the temperature in Kelvin.
k depends on the temperature, so, we can divide the k of two different temperatures:
Applying natural logathim in both sides of the equations:
ln(k1/k2) = Ea/RT2 - Ea/RT1
ln(k1/k2) = (Ea/R)x(1/T2 - 1/T1)
R = 8.314 J/mol.K
ln(2.46/47.5) = (Ea/8.314)x(1/528 - 1/492)
ln(0.052) = (Ea/8.314)x(-1.38x
-1.67xxEa = -2.95
Ea = 177x10³ J/mol
To find ko, we just need to substitute Ea in one of the specific reaction rate equation:
ko = J/mol