Answer:
See explanation and images attached
Explanation:
a) In the mechanism for the acid catalysed esterification of propanoic acid using ethanol, we can see that the first step is the protonation of the acid followed by nucleophillic attack of the alcohol. Loss of water and consequent deprotonation regenerates the acid catalyst. We can see the fate of the 18O labelled ethanol in the mechanism shown.
b) In the second mechanism, an unnamed ester is hydrolysed using an acid catalyst. The attack of the acid and subsequent nucleophillic attack of water labelled with 18O leads to the incorporation of this 18O into the product acid as shown in the mechanism attached to this answer.
Answer: It is important to wet the filter paper in the Buchner funnel first with cold re crystallization solvent before the re crystallization mixture being filtered to minimize gaps around the edges of the filter paper which can prevent mechanical impurities from passing through. This gives better filtration where most impurities can be filtered. Furthermore, it provides good vacuum.
Answer:
a)
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b)
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Explanation:
A)
Remember that positive number superscripts mean electrons lack and negative numbers mean electrons 'excess' (if we compare it with the neutral element). So, for the case of Fe2+ which is converted to Fe3+, we know that in Fe2+ there is a two electrons lack, while in Fe3+ there is a 3 electrons lack; it means that Fe2+ was converted to Fe3+ but releasing one electron:
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The same analysis is applied to Br2; Br2 is a molecule which is said to have a zero superscript because it is an apolar covalent bond; and it is converted to Br-, which, according to what I wrote above, means that there is a one electron excess. So, Br2 must have received an electron in order to change to Br-; but Br2 can't change to Br- as simple as that because Br2 is a molecule, not an atom; it is a molecule that has two Br atoms, so, Br2 must give two Br- ions as products, but receiving one electron for each one:
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b)
Applying the same, in Mg2+ there is a 2 electrons lack, and in Mg is not electron lack (its superscript is zero), so Mg must have released two electrons in order to change to Mg2+:
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Cr3+ has a 3 electrons lack, and Cr2+ a two electrons one, so, Cr3+ must receive an electron to convert to Cr2+:
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It’s the first 1 M yea it’s the first one
The answer is statement #3.
