Answer:
The pressure of the gas is 2.11 atm.
Explanation:
From the given,
Therefore, The pressure of the gas is 2.11 atm.
Answer:
Explanation:
All three lighter boron trihalides, BX3 (X = F, Cl, Br), form stable adducts with common Lewis bases. Their relative Lewis acidities can be evaluated in terms of the relative exothermicities of the adduct-forming reaction. Such measurements have revealed the following sequence for the Lewis acidity: BF3 < BCl3 < BBr3 (in other words, BBr3 is the strongest Lewis acid).
This trend is commonly attributed to the degree of π-bonding in the planar boron trihalide that would be lost upon pyramidalization (the conversion of the trigonal planar geometry to a tetrahedral one) of the BX3 molecule, which follows this trend: BF3 > BCl3 > BBr3 (that is, BBr3 is the most easily pyramidalized). The criteria for evaluating the relative strength of π-bonding are not clear, however. One suggestion is that the F atom is small compared to the larger Cl and Br atoms, and the lone pair electron in the 2pzorbital of F is readily and easily donated, and overlaps with the empty 2pz orbital of boron. As a result, the [latex]\pi[/latex] donation of F is greater than that of Cl or Br. In an alternative explanation, the low Lewis acidity for BF3 is attributed to the relative weakness of the bond in the adducts F3B-L.
M/V=D
65.14/35.4≈1.84
The density of the sulfuric acid would be about 1.84g/mL
KH₂PO₄ hydrolyzes as;
H₂PO₄⁻ + H₂O ↔ H₃PO₄ + OH⁻
Let x amount of H₂PO₄⁻ has reacted with water then,
Kb₁ = [H₃PO₄][OH⁻] / [H₂PO₄⁻]
[H₂PO₄⁻] = 0.8-x M
Kb₁ = x² / (0.8 - x)
Given Ka₁ = 7.5 x 10⁻³
so Kb₁ = 1 x 10⁻¹⁴ / (7.5 x 10⁻³) = 1.33 x 10⁻¹²
From this information:
1.33 x 10⁻¹² = x² / 0.8
x = [OH⁻] = 1.03 x 10⁻⁶ M
pOH = - log (1.03 x 10⁻⁶) = 5.99
pH = 14 - pOH = 14 - 5.99 = 8.01
