Answer: A) This reaction will be spontaneous only at high temperatures
Explanation:
= +ve, reaction is non spontaneous
= -ve, reaction is spontaneous
= 0, reaction is in equilibrium
Using Gibbs Helmholtz equation:
Given :
Thus the value of
is negative and spontaneous when temperature is high.
The dichloromethane (DCM) has less density than water and also the polarity of water is much more than DCM. So the mixture of water and dichloromethane will always be a heterogeneous mixture. In the mixture dichloromethane will be always up of the water layer. The volume of the separatory funnel which contains the mixture of DCM and water must have to be more than the total volume of the liquids thus the volume of the funnel will be more than (50+50) = 100mL.
The caution have to consider during the separation are-
1. The separatory funnel have to shake well with lid and have to settle down for some times until the two liquid separated.
2. The lid should be open very slowly as the vapor pressure of DCM is more and it will float on the water.
3. After this the stopcock should be opened and slowly the water will come out first followed by DCM.
Answer:
C
Explanation:
The early ideas of the atom states that the indivisible object is hollow or is a solid object with nothing inside. The later discoveries or works of the scientists states that inside the atoms are the subatomic particles which are the electrons, protons, and neutrons.