You multiply avogadro's number to what you were given.
8.30x10^23 * 6. 0221409x10^23
=1.357*10^25
That should be the right answer but I'm not sure. It has been awhile since I have done this.
Answer: New pressure inside the flask would be 148.8 kPa.
Explanation: The combined gas law equation is given by:

As the flask is a closed flask, so the volume remains constant. Temperature is constant also.
So, the relation between pressure and number of moles becomes



- Final conditions: When additional 3 puffs of air is added

Putting the values, in above equation, we get

The correct answer is C) A substance changes color when heated, but changes back when cooled. Hope this helps.