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Answer:
The precipitate will form.
Explanation:
Let's write the equilibrium expression for the solubility product of calcium sulfate:
⇄ 
The solubility product is defined as the product of the free ions raised to the power of their coefficients, in this case:
![K_{sp}=[Ca^{2+}][SO_4^{2-}]=10^{-4.5}](https://tex.z-dn.net/?f=K_%7Bsp%7D%3D%5BCa%5E%7B2%2B%7D%5D%5BSO_4%5E%7B2-%7D%5D%3D10%5E%7B-4.5%7D)
Our idea is to find the solubility quotient, Q, and compare it to the K value. A precipitate will only form if Q > K. If Q < K, the precipitate won't form. In this case:
![Q_{sp}=[Ca^{2+}][SO_4^{2-}]=5.00\cdot10^{-2} M\cdot7.00\cdot10^{-3} M=3.5\cdot10^{-4}](https://tex.z-dn.net/?f=Q_%7Bsp%7D%3D%5BCa%5E%7B2%2B%7D%5D%5BSO_4%5E%7B2-%7D%5D%3D5.00%5Ccdot10%5E%7B-2%7D%20M%5Ccdot7.00%5Ccdot10%5E%7B-3%7D%20M%3D3.5%5Ccdot10%5E%7B-4%7D)
Now given the K value of:
Notice that:
This means the precipitate will form, as we have an excess of free ions and the equilibrium will shift towards the formation of a precipitate to decrease the amount of free ions.
Answer:
Part A: 2N₂O(g) ⇄ 2N₂(g) + O₂(g)
Part B: -r = K*[N₂O]²
Part C: K= k1*k2
Explanation:
Part A
To do the balance chemical question for the overall chemical reaction, we must sum the reaction of the steps, eliminating the intermediaries, which are the compounds that have the same amount both at reactants and products (bolded).
N₂O(g) ⇄ N₂(g) + O(g)
N₂O(g) + O(g) ⇄ N₂(g) + O₂(g)
---------------------------------------------
2N₂O(g) + O(g) ⇄ 2N₂(g) + O(g) + O₂(g)
2N₂O(g) ⇄ 2N₂(g) + O₂(g)
Part B
The velocity of the reaction (r) can be calculated based on the reactants or based on the products. Let's do it based on the disappearing of the reactant. Because it is disappearing, the variation at its concentration must be negative, so the rate will be negative.
Let's suppose its an elementary reaction, so, the concentration of the reactant must be elevated by its coefficient. And let's call the overall rate constant as K:
-r = K*[N₂O]²
Part C
Because the steps were summed, and the reactions were not multiplied by a constant or inverted, the constant K is just the multiplication of the constants of the steps:
K= k1*k2
Water has highest flow rate
