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3 years ago

Which reaction illustrates the conservation of matter during a redox reaction

Chemistry

1 answer:

Jet001 [13]3 years ago

6 0

This question is simple, answers are D and C respectively

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The vapor pressure of substance X is 100. mm Hg at 1080.°C. The vapor pressure of substance X increases to 600. mm Hg at 1220.°C

artcher [175]

Explanation:

The given data is as follows.

$P_{1}$ = 100 mm Hg or $\frac{100}{760}atm$ = 0.13157 atm

$T_{1}$ = $1080 ^{o}C$ = (1080 + 273) K = 1357 K

$T_{2}$ = $1220 ^{o}C$ = (1220 + 273) K = 1493 K

$P_{2}$ = 600 mm Hg or $\frac{600}{760}atm$ = 0.7895 atm

R = 8.314 J/K mol

According to Clasius-Clapeyron equation,

$log(\frac{P_{2}}{P_{1}}) = \frac{\Delta H_{vap}}{2.303R}[\frac{1}{T_{1}} - \frac{1}{T_{2}}$

$log(\frac{0.7895}{0.13157}) = \frac{\Delta H_{vap}}{2.303 \times 8.314 J/mol K}[\frac{1}{1357 K} - \frac{1}{1493 K}]$

$log (6) = \frac{\Delta H_{vap}}{19.147}[\frac{(1493 - 1357) K}{1493 K \times 1357 K}]$

0.77815 = $\frac{\Delta H_{vap}}{19.147J/K mol} \times 6.713 \times 10^{-5} K$

$\Delta H_{vap}$ = $2.219 \times 10^{5}$ J/mol

= $2.219 \times 10^{5}J/mol \times 10^{-3}\frac{kJ}{1 J}$

= 221.9 kJ/mol

Thus, we can conclude that molar heat of vaporization of substance X is 221.9 kJ/mol.

4 0

2 years ago

How do I "predict the colour change that would be observed if carbon dioxide gas were bubbled into a mixture of calcium oxide, b

Effectus [21]

Hey there!

Just say what color you think the mixture would look like if those elements were combined. Personally I don't know because I don't have context, but if it comes to it just pick a color :)

Good luck, have a good night.

7 0

3 years ago

Consider the reaction

SOVA2 [1]

Answer :

(a) The average rate will be:

$\frac{d[Br_2]}{dt}=9.36\times 10^{-5}M/s$

(b) The average rate will be:

$\frac{d[H^+]}{dt}=1.87\times 10^{-4}M/s$

Explanation :

The general rate of reaction is,

$aA+bB\rightarrow cC+dD$

Rate of reaction : It is defined as the change in the concentration of any one of the reactants or products per unit time.

The expression for rate of reaction will be :

$\text{Rate of disappearance of A}=-\frac{1}{a}\frac{d[A]}{dt}$

$\text{Rate of disappearance of B}=-\frac{1}{b}\frac{d[B]}{dt}$

$\text{Rate of formation of C}=+\frac{1}{c}\frac{d[C]}{dt}$

$\text{Rate of formation of D}=+\frac{1}{d}\frac{d[D]}{dt}$

$Rate=-\frac{1}{a}\frac{d[A]}{dt}=-\frac{1}{b}\frac{d[B]}{dt}=+\frac{1}{c}\frac{d[C]}{dt}=+\frac{1}{d}\frac{d[D]}{dt}$

From this we conclude that,

In the rate of reaction, A and B are the reactants and C and D are the products.

a, b, c and d are the stoichiometric coefficient of A, B, C and D respectively.

The negative sign along with the reactant terms is used simply to show that the concentration of the reactant is decreasing and positive sign along with the product terms is used simply to show that the concentration of the product is increasing.

The given rate of reaction is,

$5Br^-(aq)+BrO_3^-(aq)+6H^+(aq)\rightarrow 3Br_2(aq)+3H_2O(l)$

The expression for rate of reaction :

$\text{Rate of disappearance of }Br^-=-\frac{1}{5}\frac{d[Br^-]}{dt}$

$\text{Rate of disappearance of }BrO_3^-=-\frac{d[BrO_3^-]}{dt}$

$\text{Rate of disappearance of }H^+=-\frac{1}{6}\frac{d[H^+]}{dt}$

$\text{Rate of formation of }Br_2=+\frac{1}{3}\frac{d[Br_2]}{dt}$

$\text{Rate of formation of }H_2O=+\frac{1}{3}\frac{d[H_2O]}{dt}$

Thus, the rate of reaction will be:

$\text{Rate of reaction}=-\frac{1}{5}\frac{d[Br^-]}{dt}=-\frac{d[BrO_3^-]}{dt}=-\frac{1}{6}\frac{d[H^+]}{dt}=+\frac{1}{3}\frac{d[Br_2]}{dt}=+\frac{1}{3}\frac{d[H_2O]}{dt}$

Part (a) :

Given:

$\frac{1}{5}\frac{d[Br^-]}{dt}=1.56\times 10^{-4}M/s$

As,

$-\frac{1}{5}\frac{d[Br^-]}{dt}=+\frac{1}{3}\frac{d[Br_2]}{dt}$

and,

$\frac{d[Br_2]}{dt}=\frac{3}{5}\frac{d[Br^-]}{dt}$

$\frac{d[Br_2]}{dt}=\frac{3}{5}\times 1.56\times 10^{-4}M/s$

$\frac{d[Br_2]}{dt}=9.36\times 10^{-5}M/s$

Part (b) :

Given:

$\frac{1}{5}\frac{d[Br^-]}{dt}=1.56\times 10^{-4}M/s$

As,

$-\frac{1}{5}\frac{d[Br^-]}{dt}=-\frac{1}{6}\frac{d[H^+]}{dt}$

and,

$-\frac{1}{6}\frac{d[H^+]}{dt}=\frac{3}{5}\frac{d[Br^-]}{dt}$

$\frac{d[H^+]}{dt}=\frac{6}{5}\times 1.56\times 10^{-4}M/s$

$\frac{d[H^+]}{dt}=1.87\times 10^{-4}M/s$

5 0

3 years ago

Which elements are out of order in terms of atomic mass. co,Ni or Li,be or I,xe

valkas [14]

Answer:

The pair co,Ni is out of order in terms of atomic mass

Explanation:

For co,Ni

Atomic mass of Co = 58.9331 u

Atomic mass of Ni = 58.6934

For Li,be

Atomic mass of Li = 6.941 u

Atomic mass of be = 9.012182 u

For I,xe

Atomic mass of I = 126.90447 u

Atomic mass of Xe = 131.293 u

Hence, the pair co,Ni is out of order in terms of atomic mass

7 0

2 years ago

You are given two aqueous solutions with different ionic solutes (Solution A and Solution B). What if you are told that Solution

klio [65]

Answer:

Yes, it is possible. Let us consider an example of two solutions, that is, solution A having 20 percent mass RbCl (rubidium chloride) and solution B is having 15 percent by mass NaCl or sodium chloride.

It is found that solution A is having more concentration in comparison to solution B in terms of mass percent. The formula for mass percent is,

% by mass = mass of solute/mass of solution * 100

Now the formula for molality is,

Molality = weight of solute/molecular weight of solute * 1000/ weight of solvent in grams

Now molality of solution A is,

m = 20/121 * 1000/80 (molecular weight of RbCl is 121 grams per mole)

m = 2.07

Now the molality of solution B is,

m = 15/58.5 * 1000/85

m = 3.02

Therefore, in terms of molality, the solution B is having greater concentration (3.02) in comparison to solution A (2.07).

5 0

3 years ago