Answer:
ΔH = -20kJ
Explanation:
The enthalpy of formation of a compound is defined as the change of enthalpy during the formation of 1 mole of the substance from its constituent elements. For H₂S(g) the reaction that describes this process is:
H₂(g) + S(g) → H₂S(g)
Using Hess's law, it is possible to sum the enthalpies of several reactions to obtain the change in enthalpy of a particular reaction thus:
<em>(1) </em>H₂S(g) + ³/₂O₂(g) → SO₂(g) + H₂O(g) ΔH = -519 kJ
<em>(2) </em>H₂(g) + ¹/₂O₂(g) → H₂O(g) ΔH = -242 kJ
<em>(3) </em>S(g) + O₂(g) → SO₂(g) ΔH = -297 kJ
The sum of -(1) + (2) + (3) gives:
<em>-(1) </em>SO₂(g) + H₂O(g) → H₂S(g) + ³/₂O₂(g) ΔH = +519 kJ
<em>(2) </em>H₂(g) + ¹/₂O₂(g) → H₂O(g) ΔH = -242 kJ
<em>(3) </em>S(g) + O₂(g) → SO₂(g) ΔH = -297 kJ
<em>-(1) + (2) + (3): </em><em>H₂(g) + S(g) → H₂S(g) </em>
<em>ΔH =</em> +519kJ - 242kJ - 297kJ = <em>-20 kJ</em>
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I hope it helps!
Answer:
Rutherfords
Explanation:
The model of the atom supported by Bohr's hydrogen experiment is the Rutherford's model of the atom.
Rutherford through his experiment on gold foil suggested the atomic model of the atom. The model posits that an atom has a small positively charged center(nucleus) where nearly all the mass is concentrated.
- Surrounding the nucleus is the large space containing electrons.
- In the Bohr's model of the atom, he suggested that the extranuclear space of the atom is made up of electrons in specific spherical orbits around the nucleus.
1) As can be seen from any 1H NMR chemical shift ppm tables, hydrogens which have δ values from 2ppm to 2.3ppm are hydrogens from carbon which is bonded to a carbonyl group. From this, we can conclude that our hydrogens belong to the type, but from 2 different alkyl groups because of 2 different signals.
2) So, one alkyl group is CH3 and second one can be CH or CH2.
3) If we know that ratio between two types of hydrogens is 3:2, it can be concluded that second alkyl group is CH2.
4) Finally, we don't have any other signals and it indicates that part of the compound which continues on CH2 is exactly the same as the first part.
The ratio remains the same, 3:2 ie 6:4
