Answer:
a. Gly-Lys + Leu-Ala-Cys-Arg + Ala-Phe
b. Glu-Ala-Phe + Gly-Ala-Tyr
Explanation:
In this case, we have to remember which peptidic bonds can break each protease:
-) <u>Trypsin</u>
It breaks selectively the peptidic bond in the carbonyl group of lysine or arginine.
-) <u>Chymotrypsin</u>
It breaks selectively the peptidic bond in the carbonyl group of phenylalanine, tryptophan, or tyrosine.
With this in mind in "peptide a", the peptidic bonds that would be broken are the ones in the <u>"Lis"</u> and <u>"Arg"</u> (See figure 1).
In "peptide b", the peptidic bond that would be broken is the one in the <u>"Phe"</u> (See figure 2). The second amino acid that can be broken is <u>tyrosine</u>, but this amino acid is placed in the <u>C terminal spot</u>, therefore will not be involved in the <u>hydrolysis</u>.
We cannot solve this problem without using empirical data. These reactions have already been experimented by scientists. The standard Gibb's free energy, ΔG°, (occurring in standard temperature of 298 Kelvin) are already reported in various literature. These are the known ΔG° for the appropriate reactions.
<span>glucose-1-phosphate⟶glucose-6-phosphate ΔG∘=−7.28 kJ/mol
fructose-6-phosphate⟶glucose-6-phosphate ΔG∘=−1.67 kJ/mol
</span>
Therefore, the reaction is a two-step process wherein glucose-6-phosphate is the intermediate product.
glucose-1-phosphate⟶glucose-6-phosphate⟶fructose-6-phosphate
In this case, you simply add the ΔG°. However, since we need the reverse of the second reaction to end up with the terminal product, fructose-6-phosphate, you'll have to take the opposite sign of ΔG°.
ΔG°,total = −7.28 kJ/mol + 1.67 kJ/mol = -5.61 kJ/mol
Then, the equation to relate ΔG° to the equilibrium constant K is
ΔG° = -RTlnK, where R is the gas constant equal to 0.008317 kJ/mol-K.
-5.61 kJ./mol = -(0.008317 kJ/mol-K)(298 K)(lnK)
lnK = 2.2635
K = e^2.2635
K = 9.62
Answer:
concrete
2kj for second question
Explanation:
it's gotta be because... let me get back on it.
A. Industrial pollution, the rest are considered positive
Answer:
C6H6 has the strongest intermolecular force
i think