Answer:
ΔG°rxn = +50.8 kJ/mol
Explanation:
It is possible to obtain ΔG°rxn of a reaction at certain temperature from ΔH°rxn and S°rxn, thus:
<em>ΔG°rxn = ΔH°rxn - T×S°rxn (1)</em>
In the reaction:
2 HNO3(aq) + NO(g) → 3 NO2(g) + H2O(l)
ΔH°rxn = 3×ΔHfNO2 + ΔHfH2O - (2×ΔHfHNO3 + ΔHfNO)
ΔH°rxn = 3×33.2kJ/mol + (-285.8kJ/mol) - (2×-207.0kJ/mol + 91.3kJ/mol)}
ΔH°rxn = 136.5kJ/mol
And S°:
S°rxn = 3×S°NO2 + S°H2O - (2×S°HNO3 + S°NO)
ΔH°rxn = 3×0.2401kJ/molK + (0.0700kJ/molK) - (2×0.146kJ/molK + 0.2108kJ/molK)
ΔH°rxn = 0.2875kJ/molK
And replacing in (1) at 298K:
ΔG°rxn = 136.5kJ/mol - 298K×0.2875kJ/molK
<em>ΔG°rxn = +50.8 kJ/mol</em>
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Answer:
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<u>Answer:</u> The weak bond having slightly positive region and a slightly negative region is polar covalent bond.
<u>Explanation:</u>
Covalent bond is defined as the bond which is formed by the sharing of electrons between the atoms. <u>For Example:</u> HCl,
etc..
They are of two types:
- <u>Polar covalent bond:</u> This bond is formed when difference in electronegativity between the atoms is present. When atoms of different elements combine, it results in the formation of polar covalent bond.
In this bond, a dipole is created. More electropnegative atom will have a slight negative charge and less electronegative atom will have a slight positive charge. For Example:
etc..
- <u>Non-polar covalent bond:</u> This bond is formed when there is no difference in electronegativity between the atoms. When atoms of the same element combine, it results in the formation of non-polar covalent bond. For Example:
etc..
Hence, the weak bond having slightly positive region and a slightly negative region is polar covalent bond.
Answer:
5.7 moles of O2
Explanation:
We'll begin by writing the balanced decomposition equation for the reaction. This is illustrated below:
2KClO3 —> 2KCl + 3O2
From the balanced equation above,
2 moles of KClO3 decomposed to produce 3 moles of O2.
Next, we shall determine the number of mole of O2 produced by the reaction of 3.8 moles of KClO3.
Since 100% yield of O2 is obtained, it means that both the actual yield and theoretical yield of O2 are the same. Thus, we can obtain the number of mole of O2 produced as follow:
From the balanced equation above,
2 moles of KClO3 decomposed to produce 3 moles of O2.
Therefore, 3.8 moles of KClO3 will decompose to produce = (3.8 × 3)/2 = 5.7 moles of O2.
Thus, 5.7 moles of O2 were obtained from the reaction.