a sample of gas measures 5 liters at 1 atm. to change the volume to a 3.5 liters at constant temperature what pressure must be a
1 answer:
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Here we have to get the of the reaction at 520 K temperature.
The of the reaction is 1.705 atm
We know the relation between and
is
, where
= The equilibrium constant of the reaction in terms of partial pressure,
= The equilibrium constant of the reaction in terms of concentration and N = number of moles of gaseous products - Number of moles of gaseous reactants.
Now in this reaction, PCl₃ + Cl₂ ⇄ PCl₅
Thus number of moles of gaseous product is 1, and number of moles of gaseous reactants are 2. Thus N = |1 - 2| = 1 mole
The given value of is 4.0×10⁻²
The molar gas constant, R = 0.082 L. Atm. mol⁻¹. K⁻¹ and temperature, T = 520 K.
On plugging the values in the equation we get,
Or, = 1.705 atm
Thus, the of the reaction is 1.705 atm
Answer:
a. the maximum number of σ bonds that the atom can form is 4
b. the maximum number of p-p bonds that the atom can form is 2
Explanation:
Hybridization is the mixing of at least two nonequivalent orbitals, in this case, we have the mixing of one <em>s, 3 p </em> and <em> 2 d </em> orbitals. In hybridization the number of hybrid orbitals generated is equal to the number of pure atomic orbital, so we have 6 hybrid orbital.
The shape of this hybrid orbital is octahedral (look the attached image) , it has 4 orbital located in the plane and 2 orbital perpendicular to it.
This shape allows the formation of maximum 4 σ bond, because σ bonds are formed by orbitals overlapping end to end.
And maximum 2 p-p bonds, because p-p bonds are formed by sideways overlapping orbitals. The atom can form one with each one of the orbitals located perpendicular to the plane.
