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Anika [276]
3 years ago
14

Complete the reaction, which is part of the electron transport chain. The abbreviation FMN represents flavin mononucleotide. Use

the appropriate abbreviation for the product.
NADH + H^+ + FMN ⟶


The reactant that is reduced is_________ .


In complex III, electrons are transferred from coenzyme Q to cytochrome c, which contains iron.


QH2 + 2cyt c ( Fe3+) ⟶ Q + 2cyt c(Fex) + 2H^+


Determine the oxidation number for iron on the right side of the reaction arrow.
Chemistry
1 answer:
Margarita [4]3 years ago
4 0

Answer:

1. NADH + H⁺ + FMN + Q ⟶ NAD⁺ + FMN + QH₂

2. The reactant that is reduced is Q

3. The charge on iron on the right side is +2, Fe²⁺

Explanation:

NADH + H⁺ + FMN + Q ⟶ NAD⁺ + FMN + QH₂

The reaction above is catalysed by NADH:ubiquinone oxidoreductase (complex 1), which transfers a hydride ion from NADH to FMN, from which two electrons pass through a series of of Fe-S centers to the iron-sulfur protein N-2. Electron transfer from N-2 to Ubiquinone forms QH₂

The species in a reaction which gains hydrogen irons is reduced,   Therefore, the reactant that is reduced is Q, ubiquinone to form QH₂, ubiquinol.

To determine the oxidation number of iron on the right side of the reaction below,

QH2 + 2cyt c ( Fe3+) ⟶ Q + 2cyt c(Fex) + 2H^+

Sum of charges on the left side = Sum of charges on the right side

Sum of charges on the left side = 2 *+3 = +6

Therefore 2 * x + 2= 6

2x = 6 -2 = 4

x = 4/

x = 2

Therefore the charge on iron on the right side is +2, Fe²⁺

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7. A 26.4-ml sample of ethylene gas, C2H4, has a pres-sure of 2.50 atm at 2.5°C. If the
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Answer: 1.87 atm

Explanation:

Combined gas law is the combination of Boyle's law, Charles's law and Gay-Lussac's law.

The combined gas equation is,

\frac{P_1V_1}{T_1}=\frac{P_2V_2}{T_2}

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P_1 = initial pressure of gas = 2.50 atm

P_2 = final pressure of gas = ?

V_1 = initial volume of gas = 26.4 ml

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T_1 = initial temperature of gas = 2.5^oC=273+2.5=275.5K

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Now put all the given values in the above equation, we get:

\frac{2.50\times 26.4}{275.5}=\frac{P_2\times 36.2}{283}

P_2=1.87atm

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The standard enthalpy of formation for chlorine is zero but the standard entropy is larger than 0 because it is the elemental state of chlorine.

The standard enthalpy of formation for chlorine is zero because cl2 is the elemental state of chlorine and it does not require any energy for the formation of the standard state of chlorine.

The entropy of any system cannot be negative. It can only be positive or zero.

The entropy of a system will become zero only at a absolute zero temperature.

That's why the entropy of chlorine in elemental state is more than zero because absolutely zero temperature can't be obtained.

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