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alukav5142 [94]

2 years ago

7

1.5 What is the purpose of adding sodium carbonate to the reaction mixture? I

1 answer:

Shtirlitz [24]2 years ago

7 0

Answer: As sodium carbonate is added, bubbles of carbon dioxide form. When all the acid has been neutralised, adding sodium carbonate will no longer produce bubbles of carbon dioxide gas. The final rinsing with water should remove traces of the water soluble salt formed.

Explanation:

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Aclosed system contains an equimolar mixture of n-pentane and isopentane. Suppose the system is initially all liquid at 120°C an

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Explanation:

The given data is as follows.

T = $120^{o}C$ = (120 + 273.15)K = 393.15 K,

As it is given that it is an equimolar mixture of n-pentane and isopentane.

So, $x_{1}$ = 0.5 and $x_{2}$ = 0.5

According to the Antoine data, vapor pressure of two components at 393.15 K is as follows.

$p^{sat}_{1}$ (393.15 K) = 9.2 bar

$p^{sat}_{1}$ (393.15 K) = 10.5 bar

Hence, we will calculate the partial pressure of each component as follows.

$p_{1} = x_{1} \times p^{sat}_{1}$

= $0.5 \times 9.2 bar$

= 4.6 bar

and, $p_{2} = x_{2} \times p^{sat}_{2}$

= $0.5 \times 10.5 bar$

= 5.25 bar

Therefore, the bubble pressure will be as follows.

P = $p_{1} + p_{2}$

= 4.6 bar + 5.25 bar

= 9.85 bar

Now, we will calculate the vapor composition as follows.

$y_{1} = \frac{p_{1}}{p}$

= $\frac{4.6}{9.85}$

= 0.467

and, $y_{2} = \frac{p_{2}}{p}$

= $\frac{5.25}{9.85}$

= 0.527

Calculate the dew point as follows.

$y_{1}$ = 0.5, $y_{2}$ = 0.5

$\frac{1}{P} = \sum \frac{y_{1}}{p^{sat}_{1}}$

$\frac{1}{P} = \frac{0.5}{9.2} + \frac{0.5}{10.2}$

$\frac{1}{P}$ = 0.101966 $bar^{-1}$

P = 9.807

Composition of the liquid phase is $x_{i}$ and its formula is as follows.

$x_{i} = \frac{y_{i} \times P}{p^{sat}_{1}}$

= $\frac{0.5 \times 9.807}{9.2}$

= 0.5329

$x_{z} = \frac{y_{i} \times P}{p^{sat}_{1}}$

= $\frac{0.5 \times 9.807}{10.5}$

= 0.467

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