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Juli2301 [7.4K]
3 years ago
10

Consider the following data concerning the equation: H2O2 + 3I– + 2H+ → I3– + 2H2O [H2O2] [I–] [H+] rate I 0.100 M 5.00 × 10–4 M

1.00 × 10–2 M 0.137 M/sec II. 0.100 M 1.00 × 10–3 M 1.00 × 10–2 M 0.268 M/sec III. 0.200 M 1.00 × 10–3 M 1.00 × 10–2 M 0.542 M/sec IV. 0.400 M 1.00 × 10–3 M 2.00 × 10–2 M 1.084 M/sec Two mechanisms are proposed: I. II. Which mechanism and which step as the rate determining step would best fit the data?

Chemistry
1 answer:
otez555 [7]3 years ago
4 0

Answer:

See explaination

Explanation:

Please kindly check attachment for the step by step solution of the given problem

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The frequency factors for these two reactions are very close to each other in value. Assuming that they are the same, compute th
MrRissso [65]

The question is incomplete, complete question is :

The frequency factors for these two reactions are very close to each other in value. Assuming that they are the same, compute the ratio of the reaction rate constants for these two reactions at 25°C.

\frac{K_1}{K_2}=?

Activation energy of the reaction 1 ,Ea_1 = 14.0 kJ/mol

Activation energy of the reaction 2,Ea_1  = 11.9 kJ/mol

Answer:

0.4284 is the ratio of the rate constants.

Explanation:

According to the Arrhenius equation,

K=A\times e^{\frac{-Ea}{RT}}

The expression used with catalyst and without catalyst is,

\frac{K_2}{K_1}=\frac{A\times e^{\frac{-Ea_2}{RT}}}{A\times e^{\frac{-Ea_1}{RT}}}

\frac{K_2}{K_1}=e^{\frac{Ea_1-Ea_2}{RT}}

where,

K_2 = rate constant reaction -1

K_1 = rate constant reaction -2

Activation energy of the reaction 1 ,Ea_1 = 14.0 kJ/mol = 14,000 J

Activation energy of the reaction 2,Ea_1  = 11.9 kJ/mol = 11,900 J

R = gas constant = 8.314 J/ mol K

T = temperature = 25^oC=273+25=298 K

Now put all the given values in this formula, we get

\frac{K_1}{K_2}=e^{\frac{11,900- 14,000Jl}{8.314 J/mol K\times 298 K}}=2.3340

0.4284 is the ratio of the rate constants.

7 0
3 years ago
1. Why does cabbage juice have different colors at different pH levels?
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1:Red cabbage contains a water-soluble pigment called anthocyanin that changes color when it is mixed with an acid or a base.

2: Basic

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Which force keeps the planets in orbit?<br><br> 1. gravity<br> 2.kinetics<br> 3.mass<br> 4.friction
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Gravity is the force that keeps the planets in orbit.
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The volume of a gas-filled balloon is 30.0 L at 313 K and 1520 mm Hg pressure. What would the volume be at standard temperature
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313 k
step-by-step-explanation
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2 years ago
0.28gram of NH3 on decomposition gave 0.25gram of nitrogen and hydrogen. Find the volume of hydrogen evolved at Ntp. (2gram hydr
hodyreva [135]

The volume of H₂ evolved at NTP=0.336 L

<h3>Further explanation</h3>

Reaction

Decomposition of NH₃

2NH₃ ⇒ N₂ + 3H₂

conservation mass : mass reactants=mass product

0.28 NH₃= 0.25 N₂ + 0.03 H₂

2 g H₂ = 22.4 L

so for 0.03 g :

\tt \dfrac{0.03}{2}\times 22.4=0.336

7 0
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