Answer:
pH = 3.3
Explanation:
Buffer solutions minimize changes in pH when quantities of acid or base are added into the mix. The typical buffer composition is a weak electrolyte (wk acid or weak base) plus the salt of the weak electrolyte. On addition of acid or base to the buffer solution, the solution chemistry functions to remove the acid or base by reacting with the components of the buffer to shift the equilibrium of the weak electrolyte left or right to remove the excess hydronium ions or hydroxide ions is a way that results in very little change in pH of the system. One should note that buffer solutions do not prevent changes in pH but minimize changes in pH. If enough acid or base is added the buffer chemistry can be destroyed.
In this problem, the weak electrolyte is HNO₂(aq) and the salt is KNO₂(aq). In equation, the buffer solution is 0.55M HNO₂ ⇄ H⁺ + 0.75M KNO₂⁻ . The potassium ion is a spectator ion and does not enter into determination of the pH of the solution. The object is to determine the hydronium ion concentration (H⁺) and apply to the expression pH = -log[H⁺].
Solution using the I.C.E. table:
HNO₂ ⇄ H⁺ + KNO₂⁻
C(i) 0.55M 0M 0.75M
ΔC -x +x +x
C(eq) 0.55M - x x 0.75M + x b/c [HNO₂] / Ka > 100, the x can be
dropped giving ...
≅0.55M x ≅0.75M
Ka = [H⁺][NO₂⁻]/[HNO₂] => [H⁺] = Ka · [HNO₂]/[NO₂⁻]
=> [H⁺] = 6.80x010⁻⁴(0.55) / (0.75) = 4.99 x 10⁻⁴M
pH = -log[H⁺] = -log(4.99 x 10⁻⁴) -(-3.3) = 3.3
Solution using the Henderson-Hasselbalch Equation:
pH = pKa + log[Base]/[Acid] = -log(Ka) + log[Base]/[Acid]
= -log(6.8 x 10⁻⁴) + log[(0.75M)/(0.55M)]
= -(-3.17) + 0.14 = 3.17 + 0.14 = 3.31 ≅ 3.3
Answer:
30 moles
Explanation:
From the equation it is a one - to - one reaction
<span>0.925 grams if using hydrochloric acid in the reaction.
0.462 grams if using sulfuric acid in the reaction.
0.000 grams if using nitric acid in the reaction.
Assuming you're using HCl or a similar acid for this reaction, the equation for the reaction is:
Zn + 2 HCl ==> ZnCl2 + H2
So each mole of zinc used, produces 1 mole of hydrogen gas, or 2 moles of hydrogen atoms. So we need to look up the atomic weights of both zinc and hydrogen.
Atomic weight zinc = 65.38
Atomic weight hydrogen = 1.00794
Moles zinc = 30.0 g / 65.38 g/mol = 0.458855919 mol
Since we produce 2 moles of hydrogen atoms per mole of zinc, multiply by 2 and the atomic weight of hydrogen to get the mass of hydrogen produced. So
0.458855919 * 2 * 1.00794 = 0.92499847 grams.
Rounding to 3 significant figures gives 0.925 grams.
To show the assumption of the acid used, the balanced equation for sulfuric acid would be
Zn2 + H2SO4 ==> Zn(SO4)2 + H2
Which means that for every mole of zinc used, 1 mole of hydrogen gas is generated (half that produced via hydrochloric acid).
If nitric acid were used, the reaction is
4Zn + 10HNO3 ==> 4Zn(NO3)2 + N2O + 5H2O
Which means that NO hydrogen gas is generated.
The only justification for assuming hydrochloric acid is used is that it's a fairly common acid that's easy to obtain. But as shown above with 2 alternative acids, the amount of hydrogen gas generated is very dependent upon the exact chemical reaction occurring and asking "How many grams of hydrogen are produced if 30.0 g of zinc reacts?" is a rather silly question unless you specify EXACTLY what the reaction is.</span>
La diferensia es que los volcanes caseros no existen solo existen los verdaderos
