Question

The normal freezing point of a certain liquid Xis-7.30°C but when l02. g of iron(III) chloride (FeCl3) are dissolved in 650. g of Xthe solution freezes at -9.9°C instead. Use this information to calculate the molal freezing point depression constant Kf of X.

Answer 1

Answer:

2.7 °C.kg/mol

Explanation:

Step 1: Calculate the freezing point depression (ΔT)

The normal freezing point of a certain liquid X is-7.30°C and the solution freezes at -9.9°C instead. The freezing point depression is:

ΔT = -7.30 °C - (-9.9 °C) = 2.6 °C

Step 2: Calculate the molality of the solution (b)

We will use the following expression.

b = mass of solute / molar mass of solute × kilograms of solvent

b = 102. g / (162.2 g/mol) × 0.650 kg = 0.967 mol/kg

Step 3: Calculate the molal freezing point depression constant Kf of X

Freezing point depression is a colligative property. It can be calculated using the following expression.

ΔT = Kf × b

Kf = ΔT / b

Kf = 2.6 °C / (0.967 mol/kg) = 2.7 °C.kg/mol