Answer : The correct option is, +91 kJ/mole
Solution :
The balanced cell reaction will be,

Here copper (Cu) undergoes oxidation by loss of electrons, thus act as anode. Lead (Pb) undergoes reduction by gain of electrons and thus act as cathode.
First we have to calculate the standard electrode potential of the cell.
![E^0_{[Pb^{2+}/Pb]}=-0.13V](https://tex.z-dn.net/?f=E%5E0_%7B%5BPb%5E%7B2%2B%7D%2FPb%5D%7D%3D-0.13V)
![E^0_{[Cu^{2+}/Cu]}=+0.34V](https://tex.z-dn.net/?f=E%5E0_%7B%5BCu%5E%7B2%2B%7D%2FCu%5D%7D%3D%2B0.34V)

![E^0_{cell}=E^0_{[Pb^{2+}/Pb]}-E^0_{[Cu^{2+}/Cu]}](https://tex.z-dn.net/?f=E%5E0_%7Bcell%7D%3DE%5E0_%7B%5BPb%5E%7B2%2B%7D%2FPb%5D%7D-E%5E0_%7B%5BCu%5E%7B2%2B%7D%2FCu%5D%7D)

Now we have to calculate the standard Gibbs free energy.
Formula used :

where,
= standard Gibbs free energy = ?
n = number of electrons = 2
F = Faraday constant = 96500 C/mole
= standard e.m.f of cell = -0.47 V
Now put all the given values in this formula, we get the Gibbs free energy.

Therefore, the standard Gibbs free energy is +91 kJ/mole
The correct answer is option A. Energy cannot be created during an ordinary chemical reaction. There is no such thing as an ordinary chemical reaction. Energy cannot be created or destroyed this is according to the law of conservation of energy. It can only be transformed from one form to another form.
<span><span>The column of a fractional distillation apparatus should be
aligned vertical to get better separation because
the column is essentially longer. It will prevent channeling in the
column. </span>Therefore column efficiency will be higher if it is as
vertical as possible instead of tilted.<span> Distillation is a process used to separate a mixture of two (or
more) components. In a typical </span>fractional
distillation, a liquid mixture
is heated in the distilling flask and the
process begins.</span>
Answer:
Plants, algae, and a group of bacteria called cyanobacteria are the only organisms capable of performing photosynthesis
Answer:
d. white blood cells
Explanation:
It is the white blood cells that have the least tendency to cross the blood- brain barrier.
Blood- brain barrier is psychological barrier and restricts substances that circulate into the blood from crossing over the central nervous system.
Water, glucose as well as sodium ions can easily cross the barrier. As these are good for body supply energy to the brain.