Answer: A plot of the natural log of the concentration of the reactant as a function of time is linear.
Explanation:
Since it was explicitly stated in the question that the half life is independent of the initial concentration of the reactant then the third option must necessarily be false. Also, the plot of the natural logarithm of the concentration of reactant against time for a first order reaction is linear. In a first order reaction, the half life is independent of the initial concentration of the reactant. Hence the answer.
Answer:

Explanation:
Hello.
In this case, since the acid is monoprotic and the KOH has one hydroxyl ion only, we can see that at the equivalence point the moles of both of them are the same:

Thus, since we are given 1.70 g of the acid, we compute the moles of acid that were titrated:

Which equal the moles of KOH. In such a way, since the molarity is defined as moles over liters (M=n/V), the liters are moles over molarity (V=n/M), thus, the resulting volume is:

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Answer:
Q = 0.50
No
Left
Explanation:
At a generic reversible equation
aA + bB ⇄ cC + dD
The reaction coefficient (Q) is the ratio of the substances concentrations:
![Q = \frac{[C]^c*[D]^d}{[A]^a*[B]^b}](https://tex.z-dn.net/?f=Q%20%3D%20%5Cfrac%7B%5BC%5D%5Ec%2A%5BD%5D%5Ed%7D%7B%5BA%5D%5Ea%2A%5BB%5D%5Eb%7D)
Solids and liquid water are not considered in this calculus.
When the reaction achieves equilibrium (concentrations are constant), the Q value is named as Kc, which is the equilibrium constant of the reaction. If Q > Kc, it indicates that the concentration of the products is higher, so, the reaction must progress to the left and form more reactants; if Q < Kc, than the concentrations of the reactants, are higher, so, the reaction progress to the right.
In this case:
Q = ![\frac{[NO_2]^2}{[N_2O_4]}](https://tex.z-dn.net/?f=%5Cfrac%7B%5BNO_2%5D%5E2%7D%7B%5BN_2O_4%5D%7D)

Q = 0.50
So, Q > Kc, the reaction is not at equilibrium and it progresses to the left.