The freezing point of the solvent in a solution changes as the concentration of the solute in the solution changes (but it does not depend on the identity of either the solvent or the solute(s) particles (kind, size or charge) in the solution).
Generally, pressures lower than 1 atmosphere lower the temperature at which a substance freezes, but for water, a higher pressure gives a lower freezing point. The force from a pressure change figures into the molecular forces already at play in a substance.
The first ionization energy is the energy that the atom lost its first electrons. The energy decrease and the atom is more reactive. So from highest to lowest is Li>Na>K>Rb.
