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Pavel [41]
3 years ago
14

Help with this please.

Chemistry
1 answer:
chubhunter [2.5K]3 years ago
6 0

Answer:

a

Explanation:

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Consider the reaction between iodine gas and chlorine gas to form iodine monochloride. A reaction mixture at 298.15k initially c
uranmaximum [27]

Step 1 : Write balanced chemical equation

The balanced chemical equation for the reaction between iodine gas and chlorine gas is given below.

I_{2}  (g) + Cl_{2}  (g) ----->  2 ICl (g)

Step 2 : Set up ICE table

We will set up an ICE table for the above reaction

Following points are considered while drawing ICE table

- The initial concentration of product is assumed as 0

- The change in concentration (C) is assumed as x. Change (x) is negative for reactants and positive for products

- The coefficients in balanced equation are considered while writing C values

Check attached file for ICE table

Step 3 : Set up equilibrium constant equation

The equation for equilibrium constant can be written as

K_{eq} = \frac{[ICl]^{2}}{[I_{2}][Cl_{2}]}

Step 4 : Solving for x

Keq at 298.15 K is given as 81.9

Let us plug in the equilibrium values (E) for I₂, Cl₂ and ICl from ICE table

81.9 = \frac{(2x)^{2}}{(0.437-x) (0.269-x)}

81.9 = \frac{(2x)^{2}}{x^{2} -0.706x + 0.118}

(2x)^{2} = 81.9 [ x^{2} -0.706x + 0.118]

4x^{2} = 81.9x^{2} -57.8x +9.66

77.9x^{2} -57.8x+9.66 = 0

Solving the above equation using quadratic formula we get

x = 0.488 or x = 0.254

The value 0.488 cannot be used because the change (C) cannot be greater that initial concentration of the reactants.

Therefore the change in concentration of the gases during the reaction is 0.254 M

Hence, x = 0.254 M

From the ICE table, we know that the equilibrium concentration of ICl is 2x

[ICl]_{eq} = 2 ( 0.254) = 0.508 M

The concentration of ICl when the reaction reaches equilibrium is 0.508 M

6 0
3 years ago
"How much NH4Cl, when present in 2.00 liters of 0.200 M ammonia, will give a solution with pH = 8.20? For NH3, Kb = 1.8 x 10-5"
Andru [333]

Answer:

245.66g of NH₄Cl is the mass we need to add to obtain the desire pH

Explanation:

The mixture of NH3/NH4Cl produce a buffer. We can find the pH of a buffer using H-H equation:

pH = pKa + log [A⁻] / [HA]

<em>Where [A⁻] is the molar concentration of the base, NH₃, and [HA] molar concentration of the acid, NH₄⁺. This molar concentration can be taken as the moles of each chemical</em>

<em />

First, we need to find pKa of NH₃ using Kb. Then, the moles of NH₃ and finally replace these values in H-H equation to solve moles of NH₄Cl we need to obtain the desire pH.

  • <em>pKa NH₃/NH₄⁺</em>

pKb = - log Kb

pKb = -log 1.8x10⁻⁵ = <em>4.74</em>

pKa = 14 - pKb

pKa = 14 - 4.74

pKa = 9.26

  • <em>Moles NH₃</em>

<em>2.00L ₓ (0.200mol NH₃ / L) = 0.400 moles NH₃</em>

  • <em>H-H equation:</em>

pH = pKa + log [NH₃] / [NH₄Cl]

8.20 = 9.26 + log [0.400 moles] / [NH₄Cl]

-1.06 =  log [0.400 moles] / [NH₄Cl]

0.0087 =  [0.400 moles] / [NH₄Cl]

[NH₄Cl] = 0.400 moles / 0.0087

[NH₄Cl] = 4.59 moles of NH₄Cl we need to add to original solution to obtain a pH of 8.20. In grams (Using molar mass NH₄Cl=53.491g/mol):

4.59 moles NH₄Cl ₓ (53.491g / mol) =

<h3>245.66g of NH₄Cl is the mass we need to add to obtain the desire pH</h3>

<em />

3 0
4 years ago
Which term describes this reactions?
Salsk061 [2.6K]

Answer:

Elimination

Explanation:

Since they are removing water from the solution, it is called elimination.

5 0
3 years ago
Read 2 more answers
2Na + CaF2à 2NaF + Ca is an example of a _________ chemical reaction.
marusya05 [52]
<span>2 Na + CaF</span>₂<span> = 2 NaF + Ca

is an example of a </span>single- replacement

answer D

hope this helps!
6 0
3 years ago
How long do you boil sweetened condensed milk to make caramel?
il63 [147K]

Explanation:

Bring to the boil. Carefully place the can in the saucepan, ensuring there's enough water to completely cover the can at all times, topping up water frequently throughout the cooking process. Simmer, uncovered for 3 hours. Ensure the can is completely covered with water at all times during cooking

7 0
3 years ago
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