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pshichka [43]
2 years ago
6

3. Methyl acetate is hydrolyzed at 25 oC in acidic environment. Aliquots of equal volume are removed and titrated with NaOH solu

tion. The hydrolysis reaction is irreversible. The results are Time/s 339 1242 2745 4546 infinite Volume of base/ mL 26.34 27.80 29.70 31.81 39.81 Write the reaction of hydrolysis of methyl acetate. (3 pts.) Neglect the reverse reaction. Find the order of the hydrolysis reaction and the value of the rate constant at this temperature. (12 pts.) Total 15 pts.
Chemistry
1 answer:
avanturin [10]2 years ago
5 0

Solution :

Time (sec)       Volume of NaOH (mL)

339                           26.23

1242                         27.80

2745                        29.70

4546                         3.81

$\infty$                               39.81

Now the example of the first order kinetics w.r.t volumetric analysis is :

$k=\frac{2.303}{t} \log \left(\frac{v_{\infty}-v_0}{v_{\infty}- v_t}\right)$

Here, $v_{\infty}= \text{ volume at }\infty = 39.81$

$v_{t}= \text{ volume at time 't' } = 27.80$

$v_0$ = volume at time 0 = 0

Since the interval is not constant, we take the time interval as

$=\frac{903+1503+1801}{3}$

$=\frac{4207}{3}$

= 1402.3333

≈  1402 seconds

$k=\frac{2.303}{1402} \log \left(\frac{39.81-0}{39.81-27.80}\right)$

  $=(0.001643) \log \left(\frac{39.81}{10.01}\right)$

  = 0.001643 x 0.52045

  = 0.00082

  $= 8.55 \times 10^{-4} \ sec^{-1}$

Therefore, the first order rate constant is k $= 8.55 \times 10^{-4} \ sec^{-1}$.

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Calculate the volume of a gas at a pressure of 150 kpa if its volume at 180 kpa is 1500 L
Anastaziya [24]

Answer: 1800 L

Explanation:

Given that,

Original pressure of gas (P1) = 180 kPa

Original volume of gas (V1) = 1500 L

New pressure of gas (P2) = 150 kPa

New volume of gas (V2) = ?

Since pressure and volume are given while temperature is held constant, apply the formula for Boyle's law

P1V1 = P1V2

180 kPa x 1500 L = 150 kPa x V2

270000 kPa•L = 150 kPa•V2

Divide both sides by 150 kPa

270000 kPa•L/150 kPa = 150 kPa•V2/150 kPa

1800L = V2

Thus, the new volume of the gas is 1800 liters.

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3 years ago
48g of 02 produce how many grams of Al2O3
bixtya [17]

Taking into account the reaction stoichiometry,  102 grams of Al₂O₃ are formed when 48 grams of O₂ react.

<h3>Reaction stoichiometry</h3>

In first place, the balanced reaction is:

4 Al + 3 O₂  → 2 Al₂O₃

By reaction stoichiometry (that is, the relationship between the amount of reagents and products in a chemical reaction), the following amounts of moles of each compound participate in the reaction:

  • Al: 4 moles
  • O₂: 3 moles
  • Al₂O₃: 2 moles

The molar mass of the compounds is:

  • Al: 27 g/mole
  • O₂: 32 g/mole
  • Al₂O₃: 102 g/mole

Then, by reaction stoichiometry, the following mass quantities of each compound participate in the reaction:

  • Al: 4 moles ×27 g/mole= 108 grams
  • O₂: 3 moles ×32 g/mole= 96 grams
  • Al₂O₃: 2 moles ×102 g/mole= 204 grams

<h3>Mass of Al₂O₃ formed</h3>

The following rule of three can be applied: if by reaction stoichiometry 96 grams of O₂ form 204 grams of Al₂O₃, 48 grams of O₂ form how much mass of Al₂O₃?

mass of Al_{2} O_{3} =\frac{48 grams of O_{2} x204 grams of Al_{2} O_{3}}{96 grams of O_{2}}

<u><em>mass of Al₂O₃= 102 grams</em></u>

Finally, 102 grams of Al₂O₃ are formed when 48 grams of O₂ react.

Learn more about the reaction stoichiometry:

brainly.com/question/24741074

brainly.com/question/24653699

#SPJ1

3 0
1 year ago
You know that chemical a reacts with chemical
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The chemical reaction would most likely be written as follows:
A + B = AB
We cannot simply use the usual method of converting grams to moles since we do not have any idea on what are the identities of A and B. The only method we could use is to use the law of conservation of mass where mass inflow in a process should be equal to the mass out in the process. The total inflow of mass would be the mass of A and B and the outflow would be the product AB.  

mass of A + mass of B = mass of AB
10.0 g A + 10.0 g B = mass of AB
mass of AB = 20.0 g 
7 0
3 years ago
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