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V125BC [204]
3 years ago
5

An aqueous solution containing 5.06 g of lead(II) nitrate is added to an aqueous solution containing 6.03 g of potassium chlorid

e.Enter the balanced chemical equation for this reaction. Be sure to include all physical states.balanced chemical equation:What is the limiting reactant?lead(II) nitratepotassium chlorideThe percent yield for the reaction is 82.9% . How many grams of the precipitate are formed?precipitate formed:gHow many grams of the excess reactant remain?excess reactant remaining:
Chemistry
1 answer:
Romashka-Z-Leto [24]3 years ago
6 0

Answer:

Pb(NO3)2(aq) + 2KCl(aq) ------> 2KNO3(aq) + PbCl2(s)

3.52 g of PbCl2

3.76 g of KCl

Explanation:

The equation of the reaction is;

Pb(NO3)2(aq) + 2KCl(aq) ------> 2KNO3(aq) + PbCl2(s)

Number of moles of Pb(NO3)2 =mass/molar mass 5.06g/331.2 g/mol = 0.0153 moles

Number of moles of KCl= mass/ molar mass= 6.03g/74.5513 g/mol= 0.081 moles

Next we obtain the limiting reactant; the limiting reactant yields the least number of moles of products.

For Pb(NO3)2;

1 mole of Pb(NO3)2 yields 1 mole of PbCl2

Therefore 0.0153 moles of Pb(NO3)2 yields 0.0153 moles of PbCl2

For KCl;

2 moles of KCl yields 1 mole of PbCl2

0.081 moles of KCl yields 0.081 moles ×1/2 = 0.041 moles of PbCl2

Therefore Pb(NO3)2 is the limiting reactant.

Theoretical Mass of precipitate obtained = 0.0153 moles of PbCl2 × 278.1 g/mol = 4.25 g of PbCl2

% yield = actual yield/theoretical yield ×100

Actual yield = % yield × theoretical yield /100

Actual yield= 82.9 ×4.25/100

Actual yield = 3.52 g of PbCl2

If 1 mole of Pb(NO3) reacts with 2 moles of KCl

0.0153 moles of Pb(NO3)2 reacts with 0.0153 moles × 2 = 0.0306 moles of KCl

Amount of excess KCl= 0.081 moles - 0.0306 moles = 0.0504 moles of KCl

Mass of excess KCl = 0.0504 moles of KCl × 74.5513 g/mol = 3.76 g of KCl

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Answer:

1) 1.52 atm.

2) 647.85 K.

3) 20.56 L.

4) 1.513 mole.

5) 254.22 K = -18.77 °C.

Explanation:

  • In all this points, we should use the law of ideal gas to solve this problem: PV = nRT.
  • Where, P is the pressure (atm), V is the volume (L), n is the number of moles, R is the general gas constant (0.082 L.atm/mol.K), and T is the temperature (K).

1) In this point; n, R, and T are constants and the variables are P and V.

P and V are inversely proportional to each other that if we have two cases we get: P1V1 = P2V2.

<u><em>In our problem:</em></u>

P1 = ??? <em>(is needed to be calculated) </em>and V1 = 45.0 L.

P2 = 5.7 atm and V2 = 12.0 L.

Then, the original pressure (P1) = P2V2 / V1 = (5.7 atm x 12.0 L) / (45.0 L) = 1.52 atm.


2) In this case, n and R are the constants and the variables are P, V, and T.

P and V are inversely proportional to each other and both of them are directly proportional to the temperature of the gas that if we have two cases we get: P1V1T2 = P2V2T1.

<u><em>In our problem:</em></u>

P1 = 212.0 kPa, V1 = 32.0 L, and T1 = 20.0 °C = (20 °C + 273) = 293 K.

P2 = 300.0 kPa, V2= 50.0 L, and T2 = ??? <em>(is needed to be calculated) </em>

Then, the temperature in the second case (T2) = P2V2T1 / P1V1 = (300.0 kPa x 50.0 L x 293 K) / (212.0 kPa x 32.0 L) = 647.85 K.


3) In this case, P, n and R are the constants and the variables are V, and T.

V and T are directly proportional to each other that if we have two cases we get: V1T2 = V2T1.

<u><em>In our problem:</em></u>

V1 = 25.0 L and T1 = 65.0 °C + 273 = 338 K.

V2 = ??? <em>(is needed to be calculated) </em> and T2 = 5.0 °C + 273 = 278 K.

Herein, there is no necessary to convert T into K.

Then, the volume in the second case (V2) = V1T2 / T1 = (25.0 L x 278 °C) / (338 °C) = 20.56 L.


4) We can get the number of moles that will fill the container from: n = PV/RT.

P = 250.0 kPa, we must convert the unit from kPa to atm; <em><u>101.325 kPa = 1.0 atm</u></em>, then P = (1.0 atm x 250.0 kPa) / (101.325 kPa) = 2.467 atm.

V = 16.0 L.

R = 0.082 L.atm/mol.K.

T = 45 °C + 273 = 318 K.

Now, n = PV/RT = (2.467 atm x 16.0 L) / (0.082 L.atm/mol.K x 318 K) = 1.513 mole.


5) In this case, V, n and R are the constants and the variables are P, and T.

P and T are directly proportional to each other that if we have two cases we get: P1T2 = P2T1.

<u><em>In our problem:</em></u>

P1 = 2200.0 mmHg and T1 = ??? <em>(is needed to be calculated) </em>.

P2 = 2700.0 mmHg and T2 = 39.0 °C + 273 = 312.0 K.

Herein, there is no necessary to convert P into atm.

Then, the temperature in the morning (T1) = P1T2 / P2 = (2200.0 mmHg x 312.0 K) / (2700.0 mmHg) = 254.22 K = -18.77 °C.

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Strontium crystallizes in a face-centered cubic unit cell having an edge length of 77.43 pm. What is the atomic radius of stront
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Atomic radius of Strontium is 27.38pm

Explanation:

In a face-centered cubic structure, the edge, a, could be obtained using pythagoras theorem knowing the hypotenuse of the unit cell, b, is equal to 4r:

a² + a² = b² = (4r)²

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As edge length of Strontium is 77.43pm:

77.43pm / √8 = r

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<h3>Atomic radius of Strontium is 27.38pm</h3>

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