Answer: Option (c) is the correct answer.
Explanation:
It is known that when we tend to dilute an impure product with too much of solvent then it will lead to dissolution of the solute. As a result, the chances of formation of crystal reduces.
And, when we increase the temperature then there will occur increase in the number of collisions between the solute and solvent molecules.
Hence, solubility of the solute also increases with increase in temperature, placing it on ice bath will further reduce the crystal formation, hence no crystal should be formed in the reaction.
Thus, we can conclude that the result of crystals boiling the impure product with too much solvent and then cooling on ice is that no crystals are produced.
Answer:
The atomic number of silicon is 14 while atomic mass of carbon is 14.
Explanation:
An atom consist of electron, protons and neutrons. Protons and neutrons are present with in nucleus while the electrons are present out side the nucleus.
All these three subatomic particles construct an atom. A neutral atom have equal number of proton and electron. In other words we can say that negative and positive charges are equal in magnitude and cancel the each other. For example if neutral atom has 6 protons than it must have 6 electrons. The sum of neutrons and protons is the mass number of an atom while the number of protons are number of electrons is the atomic number of an atom.
In given atoms ¹⁴₆C and ²⁸₁₄Si the atomic mass of carbon is 14 while the atomic number of silicon is 14. It means silicon has 14 electrons or protons while carbon has 6 protons or electrons because its atomic number is 6. Carbon has 6 protons and 8 neutrons in its nucleus while silicon has 14 protons and 14 neutrons in its nucleus.
In C:
Number of neutrons + protons = 8 + 6 = 14 amu (mass number)
Number of electrons = 6
In Si:
Number of neutrons + protons = 14 + 14 = 28 amu (mass number)
Number of electrons = 14
Formic acid is the simplest carboxylic acid with a structure of HCOOH and has a pka of 3.75. The pka refers to the acidity of the molecule, which in this example refers to the molecules ability to give up the proton of the O-H. A decrease in the pka value corresponds to an increase in acidity, or an increase in the ability to give up a proton. When an acid gives up a proton, the remaining anionic species (in this case HCOO-) is called the conjugate base, and an increase in the stability of the conjugate base corresponds to an increase in acidity.
The pka of a carboxylic can be affected greatly by the presence of various functional groups within its structure. An example of an inductive effect changing the pka can be shown with trichloroacetic acid, Cl3CCOOH. This molecule has a pka of 0.7. The decrease in pka relative to formic acid is due to the presence of the Cl3C- group, and more specifically the presence of the chlorine atoms. The electronegative chlorine atoms are able to withdraw the electron density away from the oxygen atoms and towards themselves, thus helping to stabilize the negative charge and stabilize the conjugate base. This results in an increase in acidity and decrease in pka.
The same Cl3CCOOH example can be used to explain how dipoles can effect the acidity of carboxylic acids. Compared to standard acetic acid, H3CCOOH with a pka of 4.76, trichloroacetic acid is much more acidic. The difference between these structures is the presence of C-Cl bonds in place of C-H bonds. A C-Cl bond is much more polar than a C-H bond, due the large electronegativity of the chlorine atom. This results in a carbon with a partial positive charge and a chlorine with a partial negative charge. In the conjugate base of the acid, where the molecule has a negative charge localized on the oxygen atoms, the dipole moment of the C-Cl bond is oriented such that the partial positive charge is on the carbon that is adjacent to the oxygen atoms containing the negative charge. Therefore, the electrostatic attraction between the positive end of the C-Cl dipole and the negative charge of the anionic oxygen helps to stabilize the entire species. This level of stabilization is not present in acetic acid where there are C-H bonds instead of C-Cl bonds since the C-H bonds do not have a large dipole moment.
To understand how resonance can affect the pka of a species, we can simply compare the pka of a simple alcohol such as methanol, CH3OH, and formic acid, HCOOH. The pka of methanol is 16, suggesting that is is a very weak acid. Once methanol gives up that proton to become the conjugate base CH3O-, the charge cannot be stabilized in any way and is simply localized on the oxygen atom. However, with a carboxylic acid, the conjugate base, HCOO-, can stabilize the negative charge. The lone pair electrons containing the charge on the oxygen atom are able to migrate to the other oxygen atom of the carboxylic acid. The negative charge can now be shared between the two electronegative oxygen atoms, thus stabilizing the charge and decreasing the pka.
Answer:
A
Explanation:
The answer A is the best answer because it contains the most general characteristic of a chemical change.
Isotopes are atoms of the same element that have different numbers of neutrons.
