Answer:
63.05% of MgCO3.3H2O by mass
Explanation:
<em>of MgCO3.3H2O in the mixture?</em>
The difference in masses after heating the mixture = Mass of water. With the mass of water we can find its moles and the moles and mass of MgCO3.3H2O to find the mass percent as follows:
<em>Mass water:</em>
3.883g - 2.927g = 0.956g water
<em>Moles water -18.01g/mol-</em>
0.956g water * (1mol/18.01g) = 0.05308 moles H2O.
<em>Moles MgCO3.3H2O:</em>
0.05308 moles H2O * (1mol MgCO3.3H2O / 3mol H2O) =
0.01769 moles MgCO3.3H2O
<em>Mass MgCO3.3H2O -Molar mass: 138.3597g/mol-</em>
0.01769 moles MgCO3.3H2O * (138.3597g/mol) = 2.448g MgCO3.3H2O
<em>Mass percent:</em>
2.448g MgCO3.3H2O / 3.883g Mixture * 100 =
<h3>63.05% of MgCO3.3H2O by mass</h3>
B steam causes wheels to turn is correct
<u>Answer:</u> The standard free energy change of formation of 
is 92.094 kJ/mol
<u>Explanation:</u>
We are given:
Relation between standard Gibbs free energy and equilibrium constant follows:
where,
= standard Gibbs free energy = ?
R = Gas constant = 
T = temperature = ![25^oC=[273+25]K=298K](https://tex.z-dn.net/?f=25%5EoC%3D%5B273%2B25%5DK%3D298K)
K = equilibrium constant or solubility product = 
Putting values in above equation, we get:
For the given chemical equation:
The equation used to calculate Gibbs free change is of a reaction is:
![\Delta G^o_{rxn}=\sum [n\times \Delta G^o_f_{(product)}]-\sum [n\times \Delta G^o_f_{(reactant)}]](https://tex.z-dn.net/?f=%5CDelta%20G%5Eo_%7Brxn%7D%3D%5Csum%20%5Bn%5Ctimes%20%5CDelta%20G%5Eo_f_%7B%28product%29%7D%5D-%5Csum%20%5Bn%5Ctimes%20%5CDelta%20G%5Eo_f_%7B%28reactant%29%7D%5D)
The equation for the Gibbs free energy change of the above reaction is:
![\Delta G^o_{rxn}=[(2\times \Delta G^o_f_{(Ag^+(aq.))})+(1\times \Delta G^o_f_{(S^{2-}(aq.))})]-[(1\times \Delta G^o_f_{(Ag_2S(s))})]](https://tex.z-dn.net/?f=%5CDelta%20G%5Eo_%7Brxn%7D%3D%5B%282%5Ctimes%20%5CDelta%20G%5Eo_f_%7B%28Ag%5E%2B%28aq.%29%29%7D%29%2B%281%5Ctimes%20%5CDelta%20G%5Eo_f_%7B%28S%5E%7B2-%7D%28aq.%29%29%7D%29%5D-%5B%281%5Ctimes%20%5CDelta%20G%5Eo_f_%7B%28Ag_2S%28s%29%29%7D%29%5D)
We are given:
Putting values in above equation, we get:
![285.794=[(2\times 77.1)+(1\times \Delta G^o_f_{(S^{2-}(aq.))})]-[(1\times (-39.5))]\\\\\Delta G^o_f_{(S^{2-}(aq.))=92.094J/mol](https://tex.z-dn.net/?f=285.794%3D%5B%282%5Ctimes%2077.1%29%2B%281%5Ctimes%20%5CDelta%20G%5Eo_f_%7B%28S%5E%7B2-%7D%28aq.%29%29%7D%29%5D-%5B%281%5Ctimes%20%28-39.5%29%29%5D%5C%5C%5C%5C%5CDelta%20G%5Eo_f_%7B%28S%5E%7B2-%7D%28aq.%29%29%3D92.094J%2Fmol)
Hence, the standard free energy change of formation of is 92.094 kJ/mol
The answer to the question is a.
Answer:
See Explanation
Explanation:
Let us consider the first two reactions, the initial concentration of CO was held constant and the concentration of Hbn was doubled.
2.68 * 10^-3/1.34 * 10^-3 = 6.24 * 10^-4/3.12 * 10^-4
2^1 = 2^1
The rate of reaction is first order with respect to Hbn
Let us consider the third and fourth reactions. The concentration of Hbn is held constant and that of CO was tripled.
1.5 * 10^-3/5 * 10^-4 = 1.872 * 10^-3/6.24 * 10^-4
3^1 = 3^1
The reaction is also first order with respect to CO
b) The overall order of reaction is 1 + 1=2
c) The rate equation is;
Rate = k [CO] [Hbn]
d) 3.12 * 10^-4 = k [5 * 10^-4] [1.34 * 10^-3]
k = 3.12 * 10^-4 /[5 * 10^-4] [1.34 * 10^-3]
k = 3.12 * 10^-4/6.7 * 10^-7
k = 4.7 * 10^2 mmol-1 L s-1
e) The reaction occurs in one step because;
1) The rate law agrees with the experimental data.
2) The sum of the order of reaction of each specie in the rate law gives the overall order of reaction.
