Answer:
The correct option is: (D) -2.4 kJ/mol
Explanation:
<u>Chemical reaction involved</u>: 2PG ↔ PEP
Given: The standard Gibb's free energy change: ΔG° = +1.7 kJ/mol
Temperature: T = 37° C = 37 + 273.15 = 310.15 K (∵ 0°C = 273.15K)
Gas constant: R = 8.314 J/(K·mol) = 8.314 × 10⁻³ kJ/(K·mol) (∵ 1 kJ = 1000 J)
Reactant concentration: 2PG = 0.5 mM
Product concentration: PEP = 0.1 mM
Reaction quotient: ![Q_{r} =\frac{\left [ PEP \right ]}{\left [ 2PG \right ]} = \frac{0.1 mM}{0.5 mM} = 0.2](https://tex.z-dn.net/?f=Q_%7Br%7D%20%3D%5Cfrac%7B%5Cleft%20%5B%20PEP%20%5Cright%20%5D%7D%7B%5Cleft%20%5B%202PG%20%5Cright%20%5D%7D%20%3D%20%5Cfrac%7B0.1%20mM%7D%7B0.5%20mM%7D%20%3D%200.2)
<u>To find out the Gibb's free energy change at 37° C (310.15 K), we use the equation:</u>

![\Delta G = 1.7 kJ/mol + [2.303 \times (8.314 \times 10^{-3} kJ/(K.mol))\times (310.15 K)] log (0.2)](https://tex.z-dn.net/?f=%5CDelta%20G%20%3D%201.7%20kJ%2Fmol%20%2B%20%5B2.303%20%5Ctimes%20%288.314%20%5Ctimes%2010%5E%7B-3%7D%20kJ%2F%28K.mol%29%29%5Ctimes%20%28310.15%20K%29%5D%20log%20%280.2%29)
![\Delta G = 1.7 + [5.938] \times (-0.699) = 1.7 - 4.15 = (-2.45 kJ/mol)](https://tex.z-dn.net/?f=%5CDelta%20G%20%3D%201.7%20%2B%20%5B5.938%5D%20%5Ctimes%20%28-0.699%29%20%3D%201.7%20-%204.15%20%3D%20%28-2.45%20kJ%2Fmol%29)
<u>Therefore, the Gibb's free energy change at 37° C (310.15 K): </u><u>ΔG = (-2.45 kJ/mol)</u>
Answer:
the living together in more or less intimate association or close union of two dissimilar organisms (as in parasitism or commensalism) especially : mutualism.
Explanation:
hope this helps!
Answer:
q = 40.57 kJ; w = -3.10 kJ; strong H-bonds must be broken.
Explanation:
1. Heat absorbed
q = nΔH = 1 mol × (40.57 kJ/1 mol) = 40.57 kJ
2. Change in volume
V(water) = 0.018 L
pV = nRT
1 atm × V = 1 mol × 0.082 06 L·atm·K⁻¹mol⁻¹ × 373.15 K
V = 30.62 L
ΔV = V(steam) - V(water) = 30.62 L - 0.018 L = 30.60 L
3. Work done
w = -pΔV = - 1 atm × 30.60 L = -30.60 L·atm
w = -30.60 L·atm × (101.325 J/1 L·atm) = -3100 J = -3.10 kJ
4. Why the difference?
Every gas does 3.10 kJ of work when it expands at 100 °C and 1 atm.
The difference is in the heat of vaporization. Water molecules are strongly hydrogen bonded to each other, so it takes a large amount of energy to convert water from the liquid phase to the vapour phase.
Because the helium inside it is lighter than air , hence it rises up
The balloon from our breath contains carbon dioxide which is heavier than air so it doesn’t rise