Explanation:
The observable visible spectrum of Cr(acac)3 complex is different from that of
[Cr(en)3]Br3 due to strength of bonded ligand in the coordination sphere.
en is a strong field ligand compared to acac thus pairing occurs. In both the complexes
Cr is in +3 state, configuration [Ar] 3d^3. There are 3 unpaired e in Cr(acac)3 whereas 1 unpaired e in [Cr(en)3]Br3 due to pairing.
<span>Water soaks into it easily and during freeze-thaw cycles would be more likely to break apart because of the water freezing and thawing inside the rock. The water freezes and expands inside the rock, causing the surface to break off in flakes from the pressure of the expanding ice inside.</span>
This problem is describing a gas mixture whose mole fraction of hexane in nitrogen is 0.58 and which is being fed to a condenser at 75 °C and 3.0 atm, obtaining a product at 3.0 atm and 20 °C, so that the removed heat from the system is required.
In this case, it is recommended to write the enthalpy for each substance as follows:
Whereas the specific heat of liquid and gaseous n-hexane are about 200 J/(mol*K) and 160 J/(mol*K) respectively, its condensation enthalpy is 31.5 kJ/mol, boiling point is 69 °C and the specific heat of gaseous nitrogen is about 29.1 J/(mol*K) according to the NIST data tables and 
and 
are the mole fractions in the gaseous mixture. Next, we proceed to the calculation of both heat terms as shown below:
It is seen that the heat released by the nitrogen is neglectable in comparison to n-hexanes, however, a rigorous calculation is being presented. Then, we add the previously calculated enthalpies to compute the amount of heat that is removed by the condenser:
Finally we convert this result to kJ:
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Answer:
14) The edge dislocation is more plastic than the screw dislocation
15) So as to form kinks that are fast moving
Explanation:
14) Edge and screw dislocations are the two main types of mobile dislocations
The three dimensional core of the screw dislocation prevents the slipping of the layers (one over the other) in a BCC metal such that kinks are required to be formed first by thermal activation (heating) in order. The kinks are edge dislocation that move such that the screw dislocation moves forward
Hence, the edge dislocation is more plastic than the screw dislocation
15) The three dimensional structure of a screw dislocation acts like a wedge which resists the slipping of the layers in the BCC structure such that the screw dislocation needs to be highly thermally activated forming kinks before the surrounding layers can move.
speed equals wavelength times frequency so
.7 x 500 = 350
